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Crystal structure of 2-(1H-imidazol-4-yl)ethanaminium chloride.

ABSTRACT: The title mol-ecular salt, C5H10N3 (+)·Cl(-), was obtained as by-product in the attempted synthesis of a histamine derivative. The terminal amino group of the starting material is protonated. The Cimidazole-C-C-N(H3)(+) group in the cation is in an anti conformation with a torsion angle of 176.22?(10)°. In the crystal, cations and anions are linked via N-H?N and N-H-Cl hydrogen bonds, forming a two-dimensional network parallel to (10-1). A single weak C-H?Cl hydrogen bond completes a three-dimensional network.

SUBMITTER: Belfilali I

PROVIDER: S-EPMC4420062 | biostudies-literature | 2015 May

REPOSITORIES: biostudies-literature

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Crystal structure of 2-(1H-imidazol-4-yl)ethanaminium chloride.

Belfilali Imene I Yebdri Siham S Louhibi Samira S Boukli-Hacene Leila L Roisnel Thierry T

Acta crystallographica. Section E, Crystallographic communications 20150409 Pt 5

The title mol-ecular salt, C5H10N3 (+)·Cl(-), was obtained as by-product in the attempted synthesis of a histamine derivative. The terminal amino group of the starting material is protonated. The Cimidazole-C-C-N(H3)(+) group in the cation is in an anti conformation with a torsion angle of 176.22 (10)°. In the crystal, cations and anions are linked via N-H⋯N and N-H-Cl hydrogen bonds, forming a two-dimensional network parallel to (10-1). A single weak C-H⋯Cl hydrogen bond completes a three-dimen ...[more]

PMID: 25995915

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Crystal structure of 2-(1H-imidazol-3-ium-4-yl)ethanaminium dichloride, a re-determination.

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