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Crystal structure of (2E)-2-meth-oxy-imino-2-{2-[(2-methyl-phen-oxy)meth-yl]phen-yl}-N'-(4-nitro-benzyl-idene)ethano-hydrazide.

ABSTRACT: The title compound, C24H22N4O5, crystallizes with two mol-ecules in the asymmetric unit (Z' = 2) oriented almost perpendicular to each other [dihedral angle between the central core of each mol-ecule = 77.95 (3)°]. The two mol-ecules exhibit similar conformations with an extended structure. An intra-molecular C-H⋯N hydrogen bond occurs in each mol-ecule. The two mol-ecules are linked by a bifurcated N-H⋯(O,N) hydrogen bond involving the NH group in mol-ecule A as donor. They are further linked into a ribbon along the a-axis direction by further bifurcated N-H⋯(O,N) hydrogen bonds involving the NH group in mol-ecule B as donor. C-H⋯O inter-actions are also observed.

SUBMITTER: Shripanavar CS

PROVIDER: S-EPMC4438849 | biostudies-literature | 2015 Apr

REPOSITORIES: biostudies-literature

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Crystal structure of (2E)-2-meth-oxy-imino-2-{2-[(2-methyl-phen-oxy)meth-yl]phen-yl}-N'-(4-nitro-benzyl-idene)ethano-hydrazide.

Shripanavar Chetan Shrimandhar CS Butcher Ray J RJ

Acta crystallographica. Section E, Crystallographic communications 20150318 Pt 4

The title compound, C24H22N4O5, crystallizes with two mol-ecules in the asymmetric unit (Z' = 2) oriented almost perpendicular to each other [dihedral angle between the central core of each mol-ecule = 77.95 (3)°]. The two mol-ecules exhibit similar conformations with an extended structure. An intra-molecular C-H⋯N hydrogen bond occurs in each mol-ecule. The two mol-ecules are linked by a bifurcated N-H⋯(O,N) hydrogen bond involving the NH group in mol-ecule A as donor. They are further linked i ...[more]

PMID: 26029395

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