Ontology highlight
ABSTRACT:
SUBMITTER: Shahsavari S
PROVIDER: S-EPMC5662102 | biostudies-literature | 2017 May
REPOSITORIES: biostudies-literature
ChemistrySelect 20170510 13
Hindered <i>O</i>-<i>tert</i>-alkyl <i>N</i>-arylcarbamates were conveniently prepared by treating arylamines with aryl <i>tert</i>-alkyl carbonates in the presence of a strong base. The new method avoids the use of sensitive and difficult-to-access dialkyl dicarbonates and isocyanates, which are most commonly used in known methods. Instead, the stable and readily accessible alkyl aryl carbonates are used. Therefore, the new method is particularly suitable for the synthesis of <i>N</i>-arylcarba ...[more]