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Crystal structure of ammonium bis-[(pyridin-2-yl)meth-yl]ammonium dichloride.

ABSTRACT: In the title molecular salt, C12H14N3 (+)·NH4 (+)·2Cl(-), the central, secondary-amine, N atom is protonated. The bis-[(pyridin-2-yl)meth-yl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43?(8)°. In the crystal, N-H?N and N-H?Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C-H?Cl hydrogen bonds exist within the two-dimensional network.

SUBMITTER: Trischler A

PROVIDER: S-EPMC4555372 | biostudies-literature | 2015 Sep

REPOSITORIES: biostudies-literature

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Crystal structure of ammonium bis-[(pyridin-2-yl)meth-yl]ammonium dichloride.

Trischler Aaron A Oshin Kayode K Pintauer Tomislav T

Acta crystallographica. Section E, Crystallographic communications 20150829 Pt 9

In the title molecular salt, C12H14N3 (+)·NH4 (+)·2Cl(-), the central, secondary-amine, N atom is protonated. The bis-[(pyridin-2-yl)meth-yl]ammonium and ammonium cations both lie across a twofold rotation axis. The dihedral angles between the planes of the pyridine rings is 68.43 (8)°. In the crystal, N-H⋯N and N-H⋯Cl hydrogen bonds link the components of the structure, forming a two-dimensional network parallel to (010). In addition, weak C-H⋯Cl hydrogen bonds exist within the two-dimensional ...[more]

PMID: 26396908

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