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Crystal structure of the bis-(cyclo-hexyl-ammonium) succinate succinic acid salt adduct.


ABSTRACT: The crystal structure of the title salt adduct, 2C6H14N(+)·C4H4O4 (2-)·C4H6O4, consists of two cyclo-hexyl-ammonium cations, one succcinate dianion and one neutral succinic acid mol-ecule. Succinate dianions and succinic acid mol-ecules are self-assembled head-to-tail through O-H?O hydrogen bonds and adopt a syn-syn configuration, leading to a strand-like arrangement along [101]. The cyclo-hexyl-ammonium cations have a chair conformation and act as multidentate hydrogen-bond donors linking adjacent strands through inter-molecular N-H?O inter-actions to both the succinate and the succinic acid components. This results in two-dimensional supra-molecular layered structures lying parallel to (010).

SUBMITTER: Sarr M 

PROVIDER: S-EPMC4571351 | biostudies-literature | 2015 Aug

REPOSITORIES: biostudies-literature

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Crystal structure of the bis-(cyclo-hexyl-ammonium) succinate succinic acid salt adduct.

Sarr Modou M   Diasse-Sarr Aminata A   Diop Libasse L   Plasseraud Laurent L   Cattey Hélène H  

Acta crystallographica. Section E, Crystallographic communications 20150708 Pt 8


The crystal structure of the title salt adduct, 2C6H14N(+)·C4H4O4 (2-)·C4H6O4, consists of two cyclo-hexyl-ammonium cations, one succcinate dianion and one neutral succinic acid mol-ecule. Succinate dianions and succinic acid mol-ecules are self-assembled head-to-tail through O-H⋯O hydrogen bonds and adopt a syn-syn configuration, leading to a strand-like arrangement along [101]. The cyclo-hexyl-ammonium cations have a chair conformation and act as multidentate hydrogen-bond donors linking adjac  ...[more]

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