Ontology highlight
ABSTRACT:
SUBMITTER: Li X
PROVIDER: S-EPMC4612373 | biostudies-literature | 2015 Oct
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20150907 44
Rhodium(I) carbenes were generated from propargylic alcohol derivatives as the result of a dehydrative indole annulation. Depending on the choice of the electron-withdrawing group on the aniline nitrogen nucleophile, either a cyclopropanation product or dimerization product was obtained chemoselectively. Intramolecular hydroamidation occurred for the same type of propargylic alcohol derivatives when other transition-metal catalysts were employed. ...[more]