Ontology highlight
ABSTRACT:
SUBMITTER: Ortu F
PROVIDER: S-EPMC4641456 | biostudies-literature | 2015 Apr
REPOSITORIES: biostudies-literature
Chemistry (Weinheim an der Bergstrasse, Germany) 20150317 18
1,3,6,8-Tetra-tert-butylcarbazol-9-yl and 1,8-diaryl-3,6-di(tert-butyl)carbazol-9-yl ligands have been utilized in the synthesis of potassium and magnesium complexes. The potassium complexes (1,3,6,8-tBu4carb)K(THF)4 (1; carb = C12H4N), [(1,8-Xyl2-3,6-tBu2carb)K(THF)]2 (2; Xyl = 3,5-Me2C6H3) and (1,8-Mes2-3,6-tBu2carb)K(THF)2 (3; Mes = 2,4,6-Me3C6H2) were reacted with MgI2 to give the Hauser bases 1,3,6,8-tBu4carbMgI(THF)2 (4) and 1,8-Ar2-3,6-tBu2carbMgI(THF) (Ar = Xyl 5, Ar = Mes 6). Structural ...[more]