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Crystal structure of an organic-inorganic hybrid compound based on morpholinium cations and a ?-type Anderson polyanion.

ABSTRACT: A new organic-inorganic hybrid compound, penta-morpholinium hexa-hydrogen hexa-molybdoferrate(III) sulfate 3.5-hydrate, (C4H10NO)5[Fe(III)(OH)6Mo6O18](SO4)·3.5H2O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson ?-type with a central Fe(III) ion. Three of five crystallographically independent morpholinium cations are disordered over two sets of sites. An intricate network of inter-molecular N-H?O and O-H?O inter-actions between cations, POMs, sulfate anions and non-coordinating water mol-ecules creates a three-dimensional network structure.

SUBMITTER: Lukianova TJ

PROVIDER: S-EPMC4645003 | biostudies-literature | 2015 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of an organic-inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion.

Lukianova Tamara J TJ Kinzhybalo Vasyl V Pietraszko Adam A

Acta crystallographica. Section E, Crystallographic communications 20151017 Pt 11

A new organic-inorganic hybrid compound, penta-morpholinium hexa-hydrogen hexa-molybdoferrate(III) sulfate 3.5-hydrate, (C4H10NO)5[Fe(III)(OH)6Mo6O18](SO4)·3.5H2O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central Fe(III) ion. Three of five crystallographically independent morpholinium cations are disordered over two sets of sites. An intricate network of inter-molecular N-H⋯O and O-H⋯O inter-actions between cations, POMs, sulfate ...[more]

PMID: 26594507

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