Ontology highlight
ABSTRACT:
SUBMITTER: Moriwaki R
PROVIDER: S-EPMC4645026 | biostudies-literature | 2015 Nov
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20151028 Pt 11
The title chiral photochromic Schiff base compound, C21H18BrN3O, was synthesized from (R)-(+)-1-(4-bromo-phen-yl)ethyl-amine and the salicyl-aldehyde of an azo-benzene derivative. The mol-ecule corresponds to the phenol-imine tautomer, the C=N and N-C bond distances being 1.285 (3) and 1.470 (3) Å, respectively. The diazenyl group adopts a trans form, with an N=N distance of 1.256 (3) Å. The hy-droxy group is involved in intra-molecular O-H⋯N hydrogen bonding. In the crystal, C-H⋯π inter-actions ...[more]