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Crystal structure of bis-{2-[amino(iminium-yl)meth-yl]-1,1-di-methyl-guanidine} carbonate methanol disolvate.

ABSTRACT: In the title solvated mol-ecular salt, 2C4H12N5 (+)·CO3 (2-)·2CH3OH, the complete carbonate ion is generated by crystallographic twofold symmetry, with the C atom and one O atom lying on the rotation axis. The cation is twisted about the central C-N bond [C-N-C-N = -137.7?(6)°]. In the crystal, the components are linked by N-H?O, N-H?N and O-H?O hydrogen bonds, generating a three-dimensional supra-molecular network.

SUBMITTER: Dong J

PROVIDER: S-EPMC4647403 | biostudies-literature | 2015 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of bis-{2-[amino(iminium-yl)meth-yl]-1,1-di-methyl-guanidine} carbonate methanol disolvate.

Dong Jinlong J Liu Bin B Yang Binsheng B

Acta crystallographica. Section E, Crystallographic communications 20150912 Pt 10

In the title solvated mol-ecular salt, 2C4H12N5 (+)·CO3 (2-)·2CH3OH, the complete carbonate ion is generated by crystallographic twofold symmetry, with the C atom and one O atom lying on the rotation axis. The cation is twisted about the central C-N bond [C-N-C-N = -137.7 (6)°]. In the crystal, the components are linked by N-H⋯O, N-H⋯N and O-H⋯O hydrogen bonds, generating a three-dimensional supra-molecular network. ...[more]

PMID: 26594455

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