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[?-1,1'-(Butane-1,4-di-yl)di-1H-benz-imidazole-?N:N]bis-{[N,N'-bis(car-boxy-meth-yl)ethyl-enediamine-N,N'-di-acetato-?O,O',O'',N,N']mercury(II)} methanol disolvate.

ABSTRACT: The binuclear title complex, [Hg(2)(C(10)H(14)N(2)O(8))(2)(C(18)H(18)N(4))]·2CH(3)OH, lies on an inversion center with the unique Hg(II) ion coordinated in a disorted octa-hedral environment with one Hg-N bond significantly shorter than the other two. In the crystal structure, inter-molecular O-H?O hydrogen bonds link complex and solvent mol-ecules into a three-dimensional network.

SUBMITTER: Zhu XW

PROVIDER: S-EPMC2977252 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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[μ-1,1'-(Butane-1,4-di-yl)di-1H-benz-imidazole-κN:N]bis-{[N,N'-bis(car-boxy-meth-yl)ethyl-enediamine-N,N'-di-acetato-κO,O',O'',N,N']mercury(II)} methanol disolvate.

Zhu Xue-Wen XW Xiao Bo B Yin Zhi-Gang ZG Qian Heng-Yu HY Li Gang-Sen GS

Acta crystallographica. Section E, Structure reports online 20090711 Pt 8

The binuclear title complex, [Hg(2)(C(10)H(14)N(2)O(8))(2)(C(18)H(18)N(4))]·2CH(3)OH, lies on an inversion center with the unique Hg(II) ion coordinated in a disorted octa-hedral environment with one Hg-N bond significantly shorter than the other two. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link complex and solvent mol-ecules into a three-dimensional network. ...[more]

PMID: 21583370

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