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Crystal structure of [5-bromo-2-(pyridin-2-yl-?N)phenyl-?C (1)](pentane-2,4-dionato-? (2) O,O')platinum(II).

ABSTRACT: The title cyclo-metalated platinum(II) complex with 2-(4-bromo-phen-yl)pyridinato and acetyl-acetonato ligands, [Pt(C11H7BrN)(C5H7O2)], consists of two crystallographically non-equivalent dimers, each stacked by ?-? inter-actions with distances of ? 3.4?Å. In both dimers, the platinum(II) complexes are arranged anti-parallel to each other. Each complex exhibits a slightly distorted square-planar coordination environment around the central Pt(II) atom. The dihedral angles between two chelate rings including the Pt(II) atom in these complexes are 0.08?(12) and 1.54?(9)°.

SUBMITTER: Fukuda K

PROVIDER: S-EPMC4647431 | biostudies-literature | 2015 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of [5-bromo-2-(pyridin-2-yl-κN)phenyl-κC (1)](pentane-2,4-dionato-κ (2) O,O')platinum(II).

Fukuda Keito K Sugaya Tomoaki T Ishihara Koji K

Acta crystallographica. Section E, Crystallographic communications 20150930 Pt 10

The title cyclo-metalated platinum(II) complex with 2-(4-bromo-phen-yl)pyridinato and acetyl-acetonato ligands, [Pt(C11H7BrN)(C5H7O2)], consists of two crystallographically non-equivalent dimers, each stacked by π-π inter-actions with distances of ≃ 3.4 Å. In both dimers, the platinum(II) complexes are arranged anti-parallel to each other. Each complex exhibits a slightly distorted square-planar coordination environment around the central Pt(II) atom. The dihedral angles between two chelate ring ...[more]

PMID: 26594420

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