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Metal-Free Addition/Head-to-Tail Polymerization of Transient Phosphinoboranes, RPH-BH2: A Route to Poly(alkylphosphinoboranes).

ABSTRACT: Mild thermolysis of Lewis base stabilized phosphinoborane monomers R(1)R(2)P-BH2?NMe3 (R(1),R(2)=H, Ph, or tBu/H) at room temperature to 100?°C provides a convenient new route to oligo- and polyphosphinoboranes [R(1)R(2)P-BH2]n. The polymerization appears to proceed via the addition/head-to-tail polymerization of short-lived free phosphinoborane monomers, R(1)R(2)P-BH2. This method offers access to high molar mass materials, as exemplified by poly(tert-butylphosphinoborane), that are currently inaccessible using other routes (e.g. catalytic dehydrocoupling).

SUBMITTER: Marquardt C

PROVIDER: S-EPMC4648028 | biostudies-literature | 2015 Nov

REPOSITORIES: biostudies-literature

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Metal-Free Addition/Head-to-Tail Polymerization of Transient Phosphinoboranes, RPH-BH2: A Route to Poly(alkylphosphinoboranes).

Marquardt Christian C Jurca Titel T Schwan Karl-Christian KC Stauber Andreas A Virovets Alexander V AV Whittell George R GR Manners Ian I Scheer Manfred M

Angewandte Chemie (International ed. in English) 20151002 46

Mild thermolysis of Lewis base stabilized phosphinoborane monomers R(1)R(2)P-BH2⋅NMe3 (R(1),R(2)=H, Ph, or tBu/H) at room temperature to 100 °C provides a convenient new route to oligo- and polyphosphinoboranes [R(1)R(2)P-BH2]n. The polymerization appears to proceed via the addition/head-to-tail polymerization of short-lived free phosphinoborane monomers, R(1)R(2)P-BH2. This method offers access to high molar mass materials, as exemplified by poly(tert-butylphosphinoborane), that are currently i ...[more]

PMID: 26427911

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