Unknown

Dataset Information

0

Nickel-Catalyzed Cycloisomerization of Enynes: Catalyst Generation via C-H Activation of Carbene Ligands.


ABSTRACT: The combination of Ni(0) and an N-heterocyclic carbene act as a precatalyst for the cycloisomerization of enynes to afford 1,3-dienes. During the course of the reaction, a nickel hydride is formed from oxidative addition of the ortho C-H on the carbene ligand. Deuteriumn labeling studies are presented.

SUBMITTER: Tekavec TN 

PROVIDER: S-EPMC3203641 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

altmetric image

Publications

Nickel-Catalyzed Cycloisomerization of Enynes: Catalyst Generation via C-H Activation of Carbene Ligands.

Tekavec Thomas N TN   Louie Janis J  

Tetrahedron 20080701 29


The combination of Ni(0) and an N-heterocyclic carbene act as a precatalyst for the cycloisomerization of enynes to afford 1,3-dienes. During the course of the reaction, a nickel hydride is formed from oxidative addition of the ortho C-H on the carbene ligand. Deuteriumn labeling studies are presented. ...[more]

Similar Datasets

| S-EPMC4655000 | biostudies-literature
| S-EPMC5949847 | biostudies-literature
| S-EPMC3998771 | biostudies-literature
| S-EPMC2792207 | biostudies-literature
| S-EPMC3169187 | biostudies-literature
| S-EPMC10312361 | biostudies-literature
| S-EPMC2995695 | biostudies-literature
| S-EPMC4225643 | biostudies-literature
| S-EPMC11339949 | biostudies-literature
| S-EPMC6013813 | biostudies-other