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Expanding the scope of Metal-Free enantioselective allylic substitutions: Anthrones.


ABSTRACT: The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with anthrones is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and excellent enantioselectivities.

SUBMITTER: Ceban V 

PROVIDER: S-EPMC4655356 | biostudies-literature | 2015 Nov

REPOSITORIES: biostudies-literature

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Expanding the scope of Metal-Free enantioselective allylic substitutions: Anthrones.

Ceban Victor V   Tauchman Jiří J   Meazza Marta M   Gallagher Greg G   Light Mark E ME   Gergelitsová Ivana I   Veselý Jan J   Rios Ramon R  

Scientific reports 20151123


The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with anthrones is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and excellent enantioselectivities. ...[more]

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