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Synthesis and luminescence modulation of pyrazine-based gold(III) pincer complexes.

ABSTRACT: The first examples of pyrazine-based gold(III) pincer complexes are reported; their intense photoemissions can be modified by protonation, N-alkylation or metal ions, without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delayed fluorescence (TADF).

SUBMITTER: Fernandez-Cestau J

PROVIDER: S-EPMC4672750 | biostudies-literature | 2015 Dec

REPOSITORIES: biostudies-literature

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Synthesis and luminescence modulation of pyrazine-based gold(III) pincer complexes.

Fernandez-Cestau Julio J Bertrand Benoît B Blaya Maria M Jones Garth A GA Penfold Thomas J TJ Bochmann Manfred M

Chemical communications (Cambridge, England) 20151001 93

The first examples of pyrazine-based gold(III) pincer complexes are reported; their intense photoemissions can be modified by protonation, N-alkylation or metal ions, without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delayed fluorescence (TADF). ...[more]

PMID: 26425736

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