Unknown

Dataset Information

0

Crystal structure of aqua-(nitrato-κO)dioxido{2-[3-(pyridin-2-yl-κN)-1H-1,2,4-triazol-5-yl-κN (4)]phenolato-κO}uranium(VI) aceto-nitrile monosolvate monohydrate.

ABSTRACT: In the title compound, [U(C13H9N4O)(NO3)O2(H2O)]·CH3CN·H2O, the U(VI) atom is seven-coordinated in a distorted penta-gonal-bipyramidal N2O5 manner by one tridentate triazole ligand, one monodentate nitrate anion and one water mol-ecule in the equatorial plane and by two uran-yl(VI) O atoms in the axial positions. In the crystal, the U(VI) complex mol-ecule is linked to the water and aceto-nitrile solvent mol-ecules through N-H⋯N, O-H⋯O and O-H⋯N hydrogen bonds, forming a sheet structure parallel to the bc plane. The sheets are further linked by an additional O-H⋯O hydrogen bond, forming a three-dimensional network.

SUBMITTER: Vashchenko O 

PROVIDER: S-EPMC4770975 | biostudies-literature |

REPOSITORIES: biostudies-literature

Json Xml

Similar Datasets

Unknown μ-2,3,5,6-Tetra-2-pyridylpyrazine-κN,N,N:κN,N,N-bis-[(methanol-κO)(nitrato-κO,O')(nitrato-κO)cadmium(II)].
| S-EPMC2961967 | biostudies-literature
Unknown catena-Poly[[(nitrato-κO)(1,10-phenanthroline-κN,N')manganese(II)]-μ-nitrato-κO:O'].
| S-EPMC2914918 | biostudies-literature
Unknown Bis[(2-amino-phen-yl)methanol-κN,O]bis-(nitrato-κO)cobalt(II).
| S-EPMC3007975 | biostudies-literature
Unknown (Nitrato-κO,O')bis-(tryptanthrin-κN)silver(I).
| S-EPMC3274910 | biostudies-literature
Unknown Bis(μ-pyridazine-3-carboxyl-ato-κO:O')bis-[aqua-dioxido(pyridazine-3-carboxyl-ato-κN,O)uranium(VI)] dihydrate.
| S-EPMC2967926 | biostudies-literature
Unknown Crystal structure of bis-[2-(1H-benzimidazol-2-yl-κN 3)aniline-κN]bis-(nitrato-κO)cadmium(II).
| S-EPMC6775742 | biostudies-literature
Unknown Bis(2,2'-bipyridine-κN,N')(nitrato-κO)copper(II) perchlorate.
| S-EPMC3051949 | biostudies-literature
Unknown Redetermination of bis-(2-formyl-phenolato-κO,O')nickel(II) as bis-[2-(imino-meth-yl)phenolato-κN,O']nickel(II).
| S-EPMC2979995 | biostudies-literature
Unknown Bis{μ-2-[(4,6-bis{(2-hydroxy-5-methylphenyl)[(pyridin-2-yl)methyl]amino}-1,3,5-triazin-2-yl)[(pyridin-2-yl-κN)methyl]amino-κN]-4-methyl-phenolato-1:2κO:O}bis-[(nitrato-κO,O')zinc]-acetonitrile-water (2/4/1).
| S-EPMC3274916 | biostudies-literature
Unknown Tris(nitrato-κO,O')bis-(1,10-phenanthroline-κN,N')holmium(III).
| S-EPMC2961938 | biostudies-literature