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Bis[?-1-(3,5-di-chloro-pyridin-2-yl)-2-(pyridin-3-yl-methyl-idene)hydrazine]bis-[(nitrato-?O)silver(I)] aceto-nitrile disolvate.

ABSTRACT: In the centrosymmetric binuclear title complex, [Ag2(NO3)2(C11H8Cl2N4)2]·2CH3CN, the Ag(I) atom is four-coordinated and exhibits a highly distorted tetrahedral coordination sphere defined by three N atoms from two 1-(3,5-di-chloro-pyridin-2-yl)-2-(pyridin-3-yl-methyl-idene)hy-drazine ligands and one O atom from a nitrate anion. Inter-molecular N-H?O hydrogen bonds link the complex mol-ecules, resulting in a two-dimensional supra-molecular structure parallel to (001).

SUBMITTER: Guo Y

PROVIDER: S-EPMC3790340 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Bis[μ-1-(3,5-di-chloro-pyridin-2-yl)-2-(pyridin-3-yl-methyl-idene)hydrazine]bis-[(nitrato-κO)silver(I)] aceto-nitrile disolvate.

Guo Ying Y Cai Hua H

Acta crystallographica. Section E, Structure reports online 20130904 Pt 10

In the centrosymmetric binuclear title complex, [Ag2(NO3)2(C11H8Cl2N4)2]·2CH3CN, the Ag(I) atom is four-coordinated and exhibits a highly distorted tetrahedral coordination sphere defined by three N atoms from two 1-(3,5-di-chloro-pyridin-2-yl)-2-(pyridin-3-yl-methyl-idene)hy-drazine ligands and one O atom from a nitrate anion. Inter-molecular N-H⋯O hydrogen bonds link the complex mol-ecules, resulting in a two-dimensional supra-molecular structure parallel to (001). ...[more]

PMID: 24098162

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