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Broad Scope Aminocyclization of Enynes with Cationic JohnPhos-Gold(I) Complex as the Catalyst.


ABSTRACT: A practical aminocyclization of 1,6-enynes with a wide variety of substituted anilines, including N-alkyl anilines, has been achived by using cationic [JohnPhosAu(MeCN)]SbF6 as a general purpose catalyst. The resulting adducts can be easily converted into polycyclic compounds by palladium- and gold-catalyzed reactions.

SUBMITTER: Miller R 

PROVIDER: S-EPMC4782180 | biostudies-literature | 2016 Mar

REPOSITORIES: biostudies-literature

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Broad Scope Aminocyclization of Enynes with Cationic JohnPhos-Gold(I) Complex as the Catalyst.

Miller Ricarda R   Carreras Javier J   Muratore Michael E ME   Gaydou Morgane M   Camponovo Francesco F   Echavarren Antonio M AM  

The Journal of organic chemistry 20160212 5


A practical aminocyclization of 1,6-enynes with a wide variety of substituted anilines, including N-alkyl anilines, has been achived by using cationic [JohnPhosAu(MeCN)]SbF6 as a general purpose catalyst. The resulting adducts can be easily converted into polycyclic compounds by palladium- and gold-catalyzed reactions. ...[more]

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