Ontology highlight
ABSTRACT:
SUBMITTER: Pandarus V
PROVIDER: S-EPMC5754550 | biostudies-literature | 2018 Jan
REPOSITORIES: biostudies-literature
Pandarus Valerica V Ciriminna Rosaria R Gingras Geneviève G Béland François F Pagliaro Mario M Kaliaguine Serge S
ChemistryOpen 20171211 1
The new spherical sol-gel hybrid material Silia<i>Cat</i> Pd<sup>0</sup> selectively mediates the hydrogenolysis of aromatic alcohols, aldehydes, and ketones by using an ultralow catalytic amount (0.1 mol % Pd) under mild reaction conditions. The broad reaction scope as well as the catalyst's superior activity and pronounced stability open the route to green and convenient reductive deoxygenation processes of primary synthetic relevance in chemical research as well as in the fine chemical and pe ...[more]