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?-Arylation/Heteroarylation of Chiral ?-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis.


ABSTRACT: Direct access to complex, enantiopure benzylamine architectures using a synergistic iridium photoredox/nickel cross-coupling dual catalysis strategy has been developed. New C(sp(3))-C(sp(2)) bonds are forged starting from abundant and inexpensive natural amino acids.

SUBMITTER: El Khatib M 

PROVIDER: S-EPMC4795823 | biostudies-literature | 2016 Jan

REPOSITORIES: biostudies-literature

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α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis.

El Khatib Mirna M   Serafim Ricardo Augusto Massarico RA   Molander Gary A GA  

Angewandte Chemie (International ed. in English) 20151123 1


Direct access to complex, enantiopure benzylamine architectures using a synergistic iridium photoredox/nickel cross-coupling dual catalysis strategy has been developed. New C(sp(3))-C(sp(2)) bonds are forged starting from abundant and inexpensive natural amino acids. ...[more]

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