Ontology highlight
ABSTRACT:
SUBMITTER: Jarava-Barrera C
PROVIDER: S-EPMC4831668 | biostudies-literature | 2016 Jan
REPOSITORIES: biostudies-literature
ACS catalysis 20151211 1
In this report, we establish that DM-Segphos copper(I) complexes are efficient catalysts for the enantioselective borylation of <i>para</i>-quinone methides. This method provides straightforward access to chiral monobenzylic and dibenzylic boronic esters, with enantiomeric ratios up to 96:4, using a commercially available chiral phosphine. Standard manipulations of the C-B bond afford a variety of chiral diaryl derivatives. ...[more]