Ontology highlight
ABSTRACT:
SUBMITTER: Yang X
PROVIDER: S-EPMC4887130 | biostudies-literature | 2016 May
REPOSITORIES: biostudies-literature
Organic letters 20160510 10
An efficient palladium-catalyzed α-alkenylation of pyridylmethyl ethers with vinyl bromides is presented. A Pd/NIXANTPHOS-based catalyst system enables a mild and chemoselective coupling between a variety of pyridylmethyl ethers and vinyl bromides in good to excellent yields. Under the mild conditions, β,γ-unsaturated products are obtained without isomerization or Heck byproducts observed. ...[more]