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Enantioselective Synthesis of Alkyl Allyl Ethers via Palladium-Catalyzed Redox-Relay Heck Alkenylation of O-Alkyl Enol Ethers.

ABSTRACT: Herein we report a transformation that generates an array of enantiomerically enriched, alkyl allyl ethers. Cyclic, acyclic, and heteroatom-bearing alkenyl triflates undergo an enantioselective, palladium-catalyzed C-C bond formation with diverse acyclic O-alkyl enol ethers in good yields and excellent enantioselectivities.

SUBMITTER: Prater MB 

PROVIDER: S-EPMC7806183 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature

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Enantioselective Synthesis of Alkyl Allyl Ethers via Palladium-Catalyzed Redox-Relay Heck Alkenylation of <i>O</i>-Alkyl Enol Ethers.

Prater Matthew B MB   Sigman Matthew S MS  

Israel journal of chemistry 20190911 3-4

Herein we report a transformation that generates an array of enantiomerically enriched, alkyl allyl ethers. Cyclic, acyclic, and heteroatom-bearing alkenyl triflates undergo an enantioselective, palladium-catalyzed C-C bond formation with diverse acyclic <i>O</i>-alkyl enol ethers in good yields and excellent enantioselectivities. ...[more]

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