Dicyanometallates as Model Extended Frameworks.
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ABSTRACT:
SUBMITTER: Hill JA
PROVIDER: S-EPMC4894656 | biostudies-literature | 2016 May
REPOSITORIES: biostudies-literature
Publications
Dicyanometallates as Model Extended Frameworks.
Hill Joshua A JA Thompson Amber L AL Goodwin Andrew L AL
Journal of the American Chemical Society 20160427 18
We report the structures of eight new dicyanometallate frameworks containing molecular extra-framework cations. These systems include a number of hybrid inorganic-organic analogues of conventional ceramics, such as Ruddlesden-Popper phases and perovskites. The structure types adopted are rationalized in the broader context of all known dicyanometallate framework structures. We show that the structural diversity of this family can be understood in terms of (i) the charge and coordination preferen ...[more]
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