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Carbohydrate-Catalyzed Enantioselective Alkene Diboration: Enhanced Reactivity of 1,2-Bonded Diboron Complexes.

ABSTRACT: Catalytic enantioselective diboration of alkenes is accomplished with readily available carbohydrate-derived catalysts. Mechanistic experiments suggest the intermediacy of 1,2-bonded diboronates.

SUBMITTER: Fang L 

PROVIDER: S-EPMC4896641 | biostudies-literature | 2016 Mar

REPOSITORIES: biostudies-literature

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Carbohydrate-Catalyzed Enantioselective Alkene Diboration: Enhanced Reactivity of 1,2-Bonded Diboron Complexes.

Fang Lichao L   Yan Lu L   Haeffner Fredrik F   Morken James P JP  

Journal of the American Chemical Society 20160216 8

Catalytic enantioselective diboration of alkenes is accomplished with readily available carbohydrate-derived catalysts. Mechanistic experiments suggest the intermediacy of 1,2-bonded diboronates. ...[more]

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