Ontology highlight
ABSTRACT:
SUBMITTER: Tang S
PROVIDER: S-EPMC4931026 | biostudies-literature | 2016 Jun
REPOSITORIES: biostudies-literature
Nature communications 20160624
Radical involved transformations are now considered as extremely important processes in modern organic synthetic chemistry. According to the demand by atom-economic and sustainable chemistry, direct C(sp(3))-H functionalization through radical oxidative coupling represents an appealing strategy for C-C bond formations. However, the selectivity control of reactive radical intermediates is still a great challenge in these transformations. Here we show a selective radical oxidative C(sp(3))-H/C(sp) ...[more]