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Crystal structure of catena-poly[di-ammonium [di-?-oxalato-cuprate(II)]].

ABSTRACT: The structure of the title compound, {(NH₄)₂[Cu(C₂O₄)₂]} _n , at 100?K has monoclinic (P2₁/c) symmetry with the Cu^II atom on an inversion center. The compound has a polymeric structure due to long Cu?O inter-actions which create [Cu(C₂O₄)₂] chains along the a axis. The structure also displays inter-molecular N-H?O hydrogen bonding, which links these chains into a three-dimensional network.

SUBMITTER: Dickie DA

PROVIDER: S-EPMC5137607 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of catena-poly[di-ammonium [di-μ-oxalato-cuprate(II)]].

Dickie Diane A DA Kemp Richard A RA

Acta crystallographica. Section E, Crystallographic communications 20161110 Pt 12

The structure of the title compound, {(NH4)2[Cu(C2O4)2]} n , at 100 K has monoclinic (P21/c) symmetry with the CuII atom on an inversion center. The compound has a polymeric structure due to long Cu⋯O inter-actions which create [Cu(C2O4)2] chains along the a axis. The structure also displays inter-molecular N-H⋯O hydrogen bonding, which links these ...[more]

PMID: 27980829

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