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Catena-Poly[[(1,10-phenanthroline)copper(II)]-?-oxalato].


ABSTRACT: In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octa-hedral coordination geometry. The oxalate anions act as bis-bidentate ligands, bridging the Cu-phen units in zigzag chains extending parallel to [100]. Inter-chain C-H?O hydrogen bonding and ?-? stacking inter-actions [centroid-centroid distance = 3.7439?(17)?Å] assemble neighboring chains, forming a three-dimensional supra-molecular network.

SUBMITTER: Wang J 

PROVIDER: S-EPMC2983185 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[(1,10-phenanthroline)copper(II)]-μ-oxalato].

Wang Jun J   Hou Yong Y   Fang Zhi-Li ZL  

Acta crystallographica. Section E, Structure reports online 20100908 Pt 10


In the title coordination polymer, [Cu(C(2)O(4))(C(12)H(8)N(2))](n), the Cu(II) atom is six-coordinated by four O atoms from two oxalate ligands and two N atoms from one 1,10-phenanthroline (phen) ligand in a distorted octa-hedral coordination geometry. The oxalate anions act as bis-bidentate ligands, bridging the Cu-phen units in zigzag chains extending parallel to [100]. Inter-chain C-H⋯O hydrogen bonding and π-π stacking inter-actions [centroid-centroid distance = 3.7439 (17) Å] assemble neig  ...[more]

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