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Crystal structure of oxam-yl.

ABSTRACT: The title compound, C7H13N3O3S [systematic name: (Z)-methyl 2-di-methyl-amino-N-(methyl-carbamo-yloxy)-2-oxoethanimido-thio-ate], is an oxime carbamate acaride, insecticide and nematicide. The asymmetric unit comprises two independent mol-ecules, A and B. The dihedral angles between the mean planes [r.m.s. deviations = 0.0017 (A) and 0.0016?Å (B)] of the acetamide and oxyimino groups are 88.80?(8)° for A and 87.05?(8)° for B. In the crystal, N/C-H?O hydrogen bonds link adjacent mol-ecules, forming chains along the a axis. The chains are further linked by C-H?O hydrogen bonds, resulting in a three-dimensional network with alternating rows of A and B mol-ecules in the bc plane stacked along the a-axis direction. The structure was refined as an inversion twin with a final BASF parameter of 0.16?(9).

SUBMITTER: Kwon E

PROVIDER: S-EPMC5137616 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of oxam-yl.

Kwon Eunjin E Park Ki-Min KM Park Hyunjin H Kim Tae Ho TH

Acta crystallographica. Section E, Crystallographic communications 20161118 Pt 12

The title compound, C7H13N3O3S [systematic name: (Z)-methyl 2-di-methyl-amino-N-(methyl-carbamo-yloxy)-2-oxoethanimido-thio-ate], is an oxime carbamate acaride, insecticide and nematicide. The asymmetric unit comprises two independent mol-ecules, A and B. The dihedral angles between the mean planes [r.m.s. deviations = 0.0017 (A) and 0.0016 Å (B)] of the acetamide and oxyimino groups are 88.80 (8)° for A ...[more]

PMID: 27980838

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