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Crystal structure of tris-[4-(naphthalen-1-yl)phen-yl]amine.

ABSTRACT: In the title mol-ecule, C48H33N, the central N atom shows no pyramidalization, so that the N atom and the three C atoms bound to the N atom lie almost in the same plane. The three para-phenyl-ene rings bonded to the N atom are in a propeller form. All of the naphthalene ring systems are slightly bent. In the crystal, mol-ecules form an inversion dimer, through two pairs of C-H?? inter-actions, which further inter-acts with the adjacent dimer via another two pairs of C-H?? inter-actions, forming a column structure along the a axis. There are no significant inter-actions between these column structures.

SUBMITTER: Yano M

PROVIDER: S-EPMC7534244 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of tris-[4-(naphthalen-1-yl)phen-yl]amine.

Yano Masafumi M Kashiwagi Yukiyasu Y Inada Yoshinori Y Hayashi Yuki Y Mitsudo Koichi K Kubono Koji K

Acta crystallographica. Section E, Crystallographic communications 20200918 Pt 10

In the title mol-ecule, C48H33N, the central N atom shows no pyramidalization, so that the N atom and the three C atoms bound to the N atom lie almost in the same plane. The three para-phenyl-ene rings bonded to the N atom are in a propeller form. All of the naphthalene ring systems are slightly bent. In the crystal, mol-ecules form an inversion dimer, through two pairs of C-H⋯π inter-actions, which further inter-acts with the adjacent dimer via another ...[more]

PMID: 33117582

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