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Et3B-mediated and palladium-catalyzed direct allylation of ?-dicarbonyl compounds with Morita-Baylis-Hillman alcohols.

ABSTRACT: A practical and efficient palladium-catalyzed direct allylation of ?-dicarbonyl compounds with both cyclic and acyclic Morita-Baylis-Hillman (MBH) alcohols, using Et3B as a Lewis acid promoter, is described herein. A wide range of the corresponding functionalized allylated derivatives have been obtained in good yields and with high selectivity.

SUBMITTER: Abidi A 

PROVIDER: S-EPMC5238553 | biostudies-literature | 2016

REPOSITORIES: biostudies-literature

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Et<sub>3</sub>B-mediated and palladium-catalyzed direct allylation of β-dicarbonyl compounds with Morita-Baylis-Hillman alcohols.

Abidi Ahlem A   Oueslati Yosra Y   Rezgui Farhat F  

Beilstein journal of organic chemistry 20161115

A practical and efficient palladium-catalyzed direct allylation of β-dicarbonyl compounds with both cyclic and acyclic Morita-Baylis-Hillman (MBH) alcohols, using Et<sub>3</sub>B as a Lewis acid promoter, is described herein. A wide range of the corresponding functionalized allylated derivatives have been obtained in good yields and with high selectivity. ...[more]

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