Ontology highlight
ABSTRACT:
SUBMITTER: Semakin AN
PROVIDER: S-EPMC5238579 | biostudies-literature | 2016
REPOSITORIES: biostudies-literature
Semakin Artem N AN Kokuev Aleksandr O AO Nelyubina Yulia V YV Sukhorukov Alexey Yu AY Zhmurov Petr A PA Ioffe Sema L SL Tartakovsky Vladimir A VA
Beilstein journal of organic chemistry 20161121
Exhaustive Michael-type alkylations of amines and ammonia with azoalkenes (generated from α-halohydrazones) were demonstrated as an efficient approach to poly(hydrazonomethyl)amines - a novel class of polynitrogen ligands. An intramolecular cyclotrimerization of C=N bonds in tris(hydrazonomethyl)amine to the respective 1,4,6,10-tetraazaadamantane derivative was demonstrated. ...[more]