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Tris[tris-(ethane-1,2-diamine)cobalt(II)] bis-[octa-cyanidomolybdate(V)] dihydrate.

ABSTRACT: In the title compound, [Co(II)(C(2)H(8)N(2))(3)](3)[Mo(V)(CN)(8)](2)·2H(2)O, N-H?N and N-H?O hydrogen-bonding inter-actions give rise to a three-dimensional network. In the crystal structure, each Mo polyhedron has a square-anti-prismatic shape, while the Co complexes show distorted octa-hedral geometry with an occupancy of 50%. One of the Co atoms resides on a crystallographic inversion centre.

SUBMITTER: Chu CX

PROVIDER: S-EPMC2960682 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Tris[tris-(ethane-1,2-diamine)cobalt(II)] bis-[octa-cyanidomolybdate(V)] dihydrate.

Chu Chao-Xia CX Zhou Hu H Liu Lang L Yuan Ai-Hua AH

Acta crystallographica. Section E, Structure reports online 20080813 Pt 9

In the title compound, [Co(II)(C(2)H(8)N(2))(3)](3)[Mo(V)(CN)(8)](2)·2H(2)O, N-H⋯N and N-H⋯O hydrogen-bonding inter-actions give rise to a three-dimensional network. In the crystal structure, each Mo polyhedron has a square-anti-prismatic shape, while the Co complexes show distorted octa-hedral geometry with an occupancy of 50%. One of the Co atoms resides on a crystallographic inversion centre. ...[more]

PMID: 21201606

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