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Laser induced white lighting of graphene foam.

ABSTRACT: Laser induced white light emission was observed from porous graphene foam irradiated with a focused continuous wave beam of the infrared laser diode. It was found that the intensity of the emission increases exponentially with increasing laser power density, having a saturation level at ca. 1.5?W and being characterized by stable emission conditions. It was also observed that the white light emission is spatially confined to the focal point dimensions of the illuminating laser light. Several other features of the laser induced white light emission were also discussed. It was observed that the white light emission is highly dependent on the electric field intensity, allowing one to modulate the emission intensity. The electric field intensity ca. 0.5?V/?m was able to decrease the white light intensity by half. Origins of the laser-induced white light emission along with its characteristic features were discussed in terms of avalanche multiphoton ionization, inter-valence charge transfer and possible plasma build-up processes. It is shown that the laser-induced white light emission may be well utilized in new types of white light sources.

SUBMITTER: Strek W

PROVIDER: S-EPMC5256029 | biostudies-literature | 2017 Jan

REPOSITORIES: biostudies-literature

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Laser induced white lighting of graphene foam.

Strek Wieslaw W Tomala Robert R Lukaszewicz Mikolaj M Cichy Bartlomiej B Gerasymchuk Yuriy Y Gluchowski Pawel P Marciniak Lukasz L Bednarkiewicz Artur A Hreniak Dariusz D

Scientific reports 20170123

Laser induced white light emission was observed from porous graphene foam irradiated with a focused continuous wave beam of the infrared laser diode. It was found that the intensity of the emission increases exponentially with increasing laser power density, having a saturation level at ca. 1.5 W and being characterized by stable emission conditions. It was also observed that the white light emission is spatially confined to the focal point dimensions of the illuminating laser light. Several oth ...[more]

PMID: 28112254

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Project description:Realization of graphene-based sensors and electronic devices remains challenging, in part due to integration challenges with current fabrication and manufacturing processes. Thus, scalable methods for in situ fabrication of high-quality graphene-like materials are essential. Low-cost CO2 laser engravers can be used for site-selective conversion of polyimide under ambient conditions to create 3-D, rotationally disordered, few-layer, porous, graphene-like electrodes. However, the influences of non-linear parameter terms and interactions between key parameters on the graphitization process present challenges for rapid, resource-efficient optimization. An iterative optimization strategy was developed to identify promising regions in parameter space for two key parameters, laser power and scan speed, with the goal of optimizing electrode performance while maximizing scan speed and hence fabrication throughput. The strategy employed iterations of Design of Experiments Response Surface (DoE-RS) methods combined with choices of readily measurable parameters to minimize measurement resources and time. The initial DoE-RS experiment set employed visual response parameters, while subsequent iterations used sheet resistance as the optimization parameter. The final model clearly demonstrates that laser graphitization through raster scanning is a highly non-linear process requiring polynomial terms in scan speed and laser power up to fifth order. Two regions of interest in parameter space were identified using this strategy: Region 1 represents the global minimum for sheet resistance for this laser (∼16 Ω/sq), found at a low scan speed (70 mm/s) and a low average power (2.1 W) . Region 2 is a local minimum for sheet resistance (36 Ω/sq), found at higher values for scan speed (340 mm/s) and average power (3.4 W), allowing ∼5-fold reduction in write time. Importantly, these minima do not correspond to constant ratios of average laser power to scan speed. This highlights the benefits of DoE-RS methods in rapid identification of optimum parameter combinations that would be difficult to discover using traditional one-factor-at-a-time optimization. Verification data from Raman spectroscopy showed sharp 2D peaks with mean full-width-at-half-maximum intensity values <80 cm-1 for both regions, consistent with high-quality 3D graphene-like carbon. Graphene-based electrodes fabricated using the parameters from the respective regions yielded similar performance when employed as capacitive humidity sensors with hygroscopic dielectric layers. Devices fabricated using Region 1 parameters (16 Ω/sq) yielded capacitance responses of 0.78 ± 0.04 pF at 0% relative humidity (RH), increasing to 31 ± 7 pF at 85.1% RH. Region 2 devices (36 Ω/sq) showed comparable responses (0.88 ± 0.04 pF at 0% RH, 28 ± 5 pF at 85.1% RH).

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Laser induced white lighting of graphene foam.

Publications

Laser induced white lighting of graphene foam.

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