Ontology highlight
ABSTRACT:
SUBMITTER: Priyatharsini M
PROVIDER: S-EPMC5290588 | biostudies-literature | 2017 Feb
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20170131 Pt 2
The title dinuclear complex, [Re<sub>2</sub>(C<sub>13</sub>H<sub>8</sub>NOS)<sub>2</sub>(CO)<sub>6</sub>], crystallizes in two polymorphs where the 2-(1,3-benzo-thia-zol-2-yl)phenolate ligands and two carbonyl groups are <i>trans</i>- (<b>I</b>) or <i>cis</i>-arranged (<b>II</b>) with respect to the [Re<sub>2</sub>O<sub>2</sub>(CO)<sub>4</sub>] core. Polymorphs <b>I</b> and <b>II</b> exhibit a crystallographically imposed centre of symmetry and a twofold rotation axis, respectively. The structur ...[more]