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Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzyl-idene]hydrazine-carbodi-thio-ato-?2N2,S}nickel(II): crystal structure and Hirshfeld surface analysis.

ABSTRACT: The complete mol-ecule of the title hydrazine carbodi-thio-ate complex, [Ni(C19H21N2S2)2], is generated by the application of a centre of inversion. The NiII atom is N,S-chelated by two hydrazinecarbodi-thio-ate ligands, which provide a trans-N2S2 donor set that defines a distorted square-planar geometry. The conformation of the five-membered chelate ring is an envelope with the NiII atom being the flap atom. In the crystal, p-tolyl-C-H??(benzene- i Pr), i Pr-C-H??(p-tol-yl) and ?-? inter-actions [between p-tolyl rings with inter-centroid distance = 3.8051?(12)?Å] help to consolidate the three-dimensional architecture. The analysis of the Hirshfeld surface confirms the importance of H-atom contacts in establishing the packing.

SUBMITTER: Yusof EN 

PROVIDER: S-EPMC5347063 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature

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Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzyl-idene]hydrazine-carbodi-thio-ato-κ<sup>2</sup><i>N</i><sup>2</sup>,<i>S</i>}nickel(II): crystal structure and Hirshfeld surface analysis.

Yusof Enis Nadia Md EN   Ravoof Thahira B S A TB   Tahir Mohamed I M MI   Jotani Mukesh M MM   Tiekink Edward R T ER  

Acta crystallographica. Section E, Crystallographic communications 20170217 Pt 3

The complete mol-ecule of the title hydrazine carbodi-thio-ate complex, [Ni(C<sub>19</sub>H<sub>21</sub>N<sub>2</sub>S<sub>2</sub>)<sub>2</sub>], is generated by the application of a centre of inversion. The Ni<sup>II</sup> atom is <i>N</i>,<i>S</i>-chelated by two hydrazinecarbodi-thio-ate ligands, which provide a <i>trans</i>-N<sub>2</sub>S<sub>2</sub> donor set that defines a distorted square-planar geometry. The conformation of the five-membered chelate ring is an envelope with the Ni<sup>II  ...[more]

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