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Iodido-bis-(morpholine-4-carbodi-thio-ato-?(2) S,S')(1,10-phenanthroline-?(2) N,N')bis-muth(III).

ABSTRACT: The title compound, [Bi(C4H8NOS2)2I(C12H8N2)], is monomeric, with the Bi(III) atom chelated by the two S atoms of two morpholine-4-carbodi-thio-ate ligands and the two N atoms of a 1,10-phenanthroline ligand. An iodide ligand completes the coordination sphere, with the seven-coordinate Bi(III) atom adopting a highly distorted monocapped octa-hedral geometry.

SUBMITTER: Li F

PROVIDER: S-EPMC3914055 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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Iodido-bis-(morpholine-4-carbodi-thio-ato-κ(2) S,S')(1,10-phenanthroline-κ(2) N,N')bis-muth(III).

Li Feng F Yin Handong H Wu Guoxing G

Acta crystallographica. Section E, Structure reports online 20131214 Pt 1

The title compound, [Bi(C4H8NOS2)2I(C12H8N2)], is monomeric, with the Bi(III) atom chelated by the two S atoms of two morpholine-4-carbodi-thio-ate ligands and the two N atoms of a 1,10-phenanthroline ligand. An iodide ligand completes the coordination sphere, with the seven-coordinate Bi(III) atom adopting a highly distorted monocapped octa-hedral geometry. ...[more]

PMID: 24526948

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