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Triphen-yl(pyrrolidine-1-carbodi-thio-ato-?S)tin(IV).

ABSTRACT: In the title compound, [Sn(C6H5)3(C5H8NS2)], the Sn(IV) atom adopts a distorted SnC3S tetra-hedral coordination geometry [spread of bond angles = 94.43?(7)-120.74?(7)°]. A short intra-molecular Sn?S contact [3.0270?(9)?Å] occurs and two intra-molecular C-H?S inter-actions help to establish the conformation. Three of the methyl-ene groups of the pyrrolidine-1-carbodi-thio-ate ligand are disordered over two sets of sites of equal occupancy. In the crystal, very weak C-H?S inter-actions link the mol-ecules into a three-dimensional network, with both S atoms acting as acceptors.

SUBMITTER: Sirajuddin M

PROVIDER: S-EPMC3884390 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Triphen-yl(pyrrolidine-1-carbodi-thio-ato-κS)tin(IV).

Sirajuddin Muhammad M Uddin Noor N Ali Saqib S

Acta crystallographica. Section E, Structure reports online 20130817 Pt 9

In the title compound, [Sn(C6H5)3(C5H8NS2)], the Sn(IV) atom adopts a distorted SnC3S tetra-hedral coordination geometry [spread of bond angles = 94.43 (7)-120.74 (7)°]. A short intra-molecular Sn⋯S contact [3.0270 (9) Å] occurs and two intra-molecular C-H⋯S inter-actions help to establish the conformation. Three of the methyl-ene groups of the pyrrolidine-1-carbodi-thio-ate ligand are disordered over two sets of sites of equal occupancy. In the crystal, very weak C-H⋯S inter-actions link the mo ...[more]

PMID: 24426993

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