Ontology highlight
ABSTRACT:
SUBMITTER: Rong MK
PROVIDER: S-EPMC5350608 | biostudies-literature | 2017 Mar
REPOSITORIES: biostudies-literature
Organometallics 20170216 5
Highly stable iminophosphanes, obtained from alkylating nitriles and reaction of the resulting nitrilium ions with secondary phosphanes, were explored as tunable P-monodentate and 1,3-P,N bidentate ligands in rhodium complexes. X-ray crystal structures are reported for both κ<sup>1</sup> and κ<sup>2</sup> complexes with the counterion in one of them being an unusual anionic coordination polymer of silver triflate. The iminophosphane-based ruthenium(II)-catalyzed hydration of benzonitrile in 1,2- ...[more]