Ontology highlight
ABSTRACT:
SUBMITTER: Jouffroy M
PROVIDER: S-EPMC5373477 | biostudies-literature | 2016 Apr
REPOSITORIES: biostudies-literature
Organic letters 20160317 7
A highly effective method for derivatizing 2,1-borazaronaphthalene cores using ammonium alkylbis(catecholato)silicates via photoredox/nickel dual catalysis is reported. By forging C(sp)(3)-C(sp)(2) bonds via this approach, alkyl fragments with various functional groups can be introduced to the azaborine core, affording previously inaccessible heterocyclic isosteres in good to excellent yields. The base-free, room-temperature conditions outlined allow sensitive functional group tolerance, even pe ...[more]