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Synthesis and crystal structure of bis-(?-2-methyl-benzene-thiol-ato-?²S:S)bis-[meth-yl(2-methyl-benzene-thiol-ato-?S)indium(III)].

ABSTRACT: The dinuclear title compound, [In₂(CH₃)₂(C₇H₇S)₄] or [Me(2-MeC₆H₄S)In-?-(2-MeC₆H₄S)₂InMe(2-MeC₆H₄S)], was prepared from the 1:2 reaction of Me₃In and 2-MeC₆H₄SH in toluene. Its crystal structure exhibits a four-membered In₂S₂ ring core via bridging (2-MeC₆H₄S) groups. The dimeric units are further associated into a one-dimensional polymeric structure extending parallel to the a axis via inter-molecular In?S contacts. The In atoms are then in distorted trigonal-bipyramidal CS₄ bonding environments.

SUBMITTER: Briand GG

PROVIDER: S-EPMC5382603 | biostudies-literature | 2017 Apr

REPOSITORIES: biostudies-literature

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Synthesis and crystal structure of bis-(μ-2-methyl-benzene-thiol-ato-κ2S:S)bis-[meth-yl(2-methyl-benzene-thiol-ato-κS)indium(III)].

Briand Glen G GG Decken Andreas A Dickie Courtney M CM MacNeil Gregory G

Acta crystallographica. Section E, Crystallographic communications 20170310 Pt 4

The dinuclear title compound, [In2(CH3)2(C7H7S)4] or [Me(2-MeC6H4S)In-μ-(2-MeC6H4S)2InMe(2-MeC6H4S)], was prepared from the 1:2 reaction of Me3In and 2-MeC6H4SH in toluene. Its crystal structure exhibits a four-membered In2S2 ring core via bridging (2-MeC6H4S) groups. The ...[more]

PMID: 28435702

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Crystal structure of (μ-4-hy-droxy-benzene-thiol-ato-κ(2) S:S)bis-(μ-phenyl-methane-thiol-ato-κ(2) S:S)bis-[(η(6)-1-isopropyl-4-methyl-benzene)-ruthenium(II)] tetra-fluorido-borate.

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catena-Poly[[bis-(4-methyl-benzene-thiol-ato)cadium(II)]-μ-1,3-di-4-pyridylpropane].

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Crystal structure of bis-[μ-(4-meth-oxy-phen-yl)methane-thiol-ato-κ(2) S:S]bis-[chlorido-(η(6)-1-isopropyl-4-methyl-benzene)-ruthenium(II)] chloro-form disolvate.

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(μ-4-Methyl-benzene-thiol-ato-κS:S)bis-[carbon-yl(η-cyclo-penta-dien-yl)molybdenum(II)].

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