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Crystal structure of (?-4-hy-droxy-benzene-thiol-ato-?(2) S:S)bis-(?-phenyl-methane-thiol-ato-?(2) S:S)bis-[(?(6)-1-isopropyl-4-methyl-benzene)-ruthenium(II)] tetra-fluorido-borate.

ABSTRACT: The crystal structure of the dinuclear arene ruthenium title complex, [Ru2(C6H5OS)(C7H7S)2(C10H14)2]BF4, shows the two Ru(II) atoms to be bridged by two benzyl-thio-pheno-late units and one 4-hy-droxy-thio-pheno-late unit, with the remaining three coordination sites of each Ru(II) atom being occupied by p-cymene ligands, completing the typical piano-stool coordination geometry. The BF4 (-) counter-anion is surrounded by four cationic dinuclear complexes, showing an O-H?F hydrogen bond and several weak C-H?F inter-actions. This is the first example of an X-ray analysis of a mixed dinuclear tri-thiol-ate arene ruthenium(II) complex.

SUBMITTER: Stibal D

PROVIDER: S-EPMC4647355 | biostudies-literature | 2015 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of (μ-4-hy-droxy-benzene-thiol-ato-κ(2) S:S)bis-(μ-phenyl-methane-thiol-ato-κ(2) S:S)bis-[(η(6)-1-isopropyl-4-methyl-benzene)-ruthenium(II)] tetra-fluorido-borate.

Stíbal David D Süss-Fink Georg G Therrien Bruno B

Acta crystallographica. Section E, Crystallographic communications 20150912 Pt 10

The crystal structure of the dinuclear arene ruthenium title complex, [Ru2(C6H5OS)(C7H7S)2(C10H14)2]BF4, shows the two Ru(II) atoms to be bridged by two benzyl-thio-pheno-late units and one 4-hy-droxy-thio-pheno-late unit, with the remaining three coordination sites of each Ru(II) atom being occupied by p-cymene ligands, completing the typical piano-stool coordination geometry. The BF4 (-) counter-anion is surrounded by four cationic dinuclear complexes, showing an O-H⋯F hydrogen bond and severa ...[more]

PMID: 26594399

Similar Datasets

Poly[[nona-aqua-bis-(?-5-hy-droxy-benzene-1,3-di-carboxyl-ato)(5-hy-droxy-benzene-1,3-di-carboxyl-ato)dicerium(III)] hexa-hydrate].

Project description:In the title coordination polymer, {[Ce2(C8H4O5)3(H2O)9]·6H2O} n , the asymmetric unit is formed by two Ce(III) atoms, three 5-hy-droxy-benzene-1,3-di-carboxyl-ate ligands, nine coordinating water mol-ecules and six water mol-ecules of crystallization. The two Ce(III) atoms are bridged by 5-hy-droxy-benzene-1,3-di-carboxyl-ate ligands acting in a bis-bidentate coordination mode, generating infinite chains along [101]. Both independent metal atoms are nine-coordinated, one by four O atoms from the carboxyl-ate groups of two bridging 5-hy-droxy-benzene-1,3-di-carboxyl-ate ligands and five O atoms from water mol-ecules, generating a tricapped trigonal-prismatic geometry. The coordination around the second Ce(III) atom is similar, except that one of the water mol-ecules is replaced by an O atom from an additional 5-hy-droxy-benzene-1,3-di-carboxyl-ate ligand acting in a monodentate coordination mode and forming a capped square-anti-prismatic geometry.

| S-EPMC4011209 | biostudies-literature

Crystal structure of bis-[?-(4-meth-oxy-phen-yl)methane-thiol-ato-?(2) S:S]bis-[chlorido-(?(6)-1-isopropyl-4-methyl-benzene)-ruthenium(II)] chloro-form disolvate.

Project description:The mol-ecular structure of the title complex, [Ru2(C8H9OS)2Cl2(C10H14)2]·2CHCl3 or (p-MeC6H4Pr (i) )2Ru2(SCH2-p-C6H5-OCH3)2Cl2·2CHCl3, shows inversion symmetry. The two symmetry-related Ru(II) atoms are bridged by two 4-meth-oxy-?-toluene-thiol-ato [(4-meth-oxy-phen-yl)methane-thiol-ato] units. One chlorido ligand and the p-cymene ligand complete the typical piano-stool coordination environment of the Ru(II) atom. In the crystal, the CH moiety of the chloro-form mol-ecule inter-acts with the chlorido ligand of the dinuclear complex, while one Cl atom of the solvent inter-acts more weakly with the methyl group of the bridging 4-meth-oxy-?-toluene-thiol-ato unit. This assembly leads to the formation of supra-molecular chains extending parallel to [021].

| S-EPMC4647371 | biostudies-literature

Crystal structure of bis-(?-<i>N</i>-hy-droxy-picolin-amid-ato)bis-[bis-(<i>N</i>-hy-droxy-picolinamide)-sodium].

Project description:The title compound, [Na2(C6H5N2O2)2(C6H6N2O2)4], is a centrosymmetric coordination dimer based on the sodium(I) salt of N-hy-droxy-picolinamide. The mol-ecule has an {Na2O6(?-O)2} core with two bridging carbonyl O atoms and two hydroxamate O atoms of two mono-deprotonated residues of N-hy-droxy-picolinamide, while two neutral N-hy-droxy-picolinamide mol-ecules are coordinated in a monodentate manner to each sodium ion via the carbonyl O atoms [the Na-O distances range from 2.3044?(2) to 2.3716?(2)?Å]. The penta-coordinated sodium ion exhibits a distorted trigonal-pyramidal coordination polyhedron. In the crystal, the coordination dimers are linked into chains along the c axis via N-H?O and N-H?N hydrogen bonds; the chains are linked into a two-dimensional framework parallel to (100) via weak C-H?O and ?-? stacking inter-actions.

| S-EPMC5209763 | biostudies-literature

Bis(2,2'-bipyridine)(pyridin-2-olato)ruthenium(II) hexa-fluorido-phosphate benzene hemisolvate.

Project description:In the title compound, [Ru(C(5)H(4)NO)(C(10)H(8)N(2))(2)]PF(6)·0.5C(6)H(6), the Ru(2+) cation has a distorted octa-hedral RuN(5)O coordination environment. This complex is more distorted than the closely related ruthenium complex containing a pyridine-2-thiol-ate ligand [Santra et al. (1997 ?). J. Chem. Soc. Dalton Trans. pp. 1387-1393]. The distortion is caused by the difference in size between the O and S atoms. The benzene solvent mol-ecule is situated on a twofold rotation axis.

| S-EPMC3238613 | biostudies-literature

Poly[[?-aqua-bis-(?-4,4'-bipyridine-?N:N')bis-(?-3-hy-droxy-adamantane-1-carboxyl-ato-?O:O')bis-(3-hy-droxy-adamantane-1-carboxyl-ato-?O)dicobalt(II)] hepta-hydrate].

Project description:The title coordination compound, {[Co(C(11)H(15)O(3))(4)(C(10)H(8)N(2))(2)(H(2)O)]·7H(2)O}(n), consists of a pair of Co(II) atoms, four 3-hy-droxy-adamantane-1-carboxyl-ate anions (L), one water mol-ecule, two bridging 4,4'-bipyridine (4,4'-bpy) ligands and seven uncoordinated water mol-ecules. Both of the Co(II) ions are coordinated in a distorted octa-hedral geometry. Four L ligands bind to each pair of Co(II) atoms in a plane, two of which bridge the two Co(II) atoms as bidentate groups while the other two coordinate to a single Co(II) atom in a monodentate mode. Two half-mol-ecules of 4,4'-bipyridine coordinate the Co(II) atoms from the upside and underside. The packing features extensice O-H?O hydrogen bonding.

| S-EPMC3089202 | biostudies-literature

[2-(sec-Butyl-imino-meth-yl)quinoline]-chlorido(?-1-isopropyl-4-methyl-benzene)-ruthenium(II) hexa-fluorido-phosphate.

Project description:In the title compound, [RuCl(C(10)H(14))(C(14)H(16)N(2))]PF(6), the aromatic ring of the isopropyl-methyl-benzene fragment shows an ?(6)-arene coordination to the ruthenium atom. Its coordination sphere is completed by a chloride ligand and 2-(sec-butyl-imino-meth-yl)quinoline. The dihedral angle between the ?(6)-arene ring and the quinoline Schiff base is 45.64?(9)°. The sec-butyl substituent and the PF(6) (-) anion are disordered over two positions with ratios of 0.595?(11):0.405?(11) and 0.752?(8):0.248?(8), respectively.

| S-EPMC3008139 | biostudies-literature

Crystal structure of bis-[1-(2-hy-droxy-eth-yl)-2-methyl-5-nitro-1H-imidazole-?N (3)]silver(I) tetra-fluorido-borate methanol monosolvate.

Project description:1-(2-Hy-droxy-eth-yl)-2-methyl-5-nitro-1H-imidazole (metronidazole, MET) is a medication that is used to treat infections by a variety of anaerobic organisms, but there are relatively few reports of the structures of metal compounds that exhibit coordination of metronidazole. We have demonstrated that MET reacts with AgBF4 to give [Ag(MET)2]BF4·CH3OH, in which the Ag(I) cation is coordinated by two MET ligands with a trans arrangement. The structure of [Ag(MET)2]BF4 exhibits some inter-esting differences from its nitrate counterpart, [Ag(MET)2]NO3 [Fun et al. (2008). Acta Cryst. E64, m668]. For instance, although the two MET ligands of both [Ag(MET)2]BF4 and [Ag(MET)2]NO3 are almost coplanar, the former compound has an anti-like geometry with a mol-ecular inversion center, but the latter has a syn-like arrangement. In the crystal, the BF4 (-) anion is linked by an O-H?F hydrogen bond to the methanol solvent molecule, which is, in turn, linked to the cation by an O-H?O hydrogen bond; the components of the structure are linked by O-H?O hydrogen bonds, forming chains along [001]. One of the MET ligands and the BF4 (-) anion are disordered over two sets of sites with ratios of refined occupancies 0.501?(17):0.499?(17) and 0.539?(19):0.461?(19), respectively.

| S-EPMC4350687 | biostudies-literature

Poly[[diaqua-bis-(μ(3)-3-carboxyl-ato-4-hy-droxy-benzene-sulfonato)-tri-μ(2)-pyrazine-tetra-silver(I)] dihydrate].

Project description:The title coordination polymer, {[Ag(4)(C(7)H(4)O(6)S)(2)(C(4)H(4)N(2))(3)(H(2)O)(2)]·2H(2)O}(n), contains two independent Ag(I) ions. One Ag(I) ion is coordinated by one O atom from a 3-carboxyl-ato-4-hy-droxy-benzene-sulfonate (L) ligand, two N atoms from two pyrazine ligands and a water mol-ecule. The other Ag(I) ion is coordinated by two O atoms from two L ligands and one N atom from a pyrazine ligand. One of the pyrazine ligands lies on an inversion center. The L and pyrazine ligands link the Ag(I) ions into polymeric layers parallel to the ac plane. The layers are connected by inter-molecular O-H⋯O hydrogen bonds. An intra-molecular O-H⋯O hydrogen bond is also present in the L ligand.

| S-EPMC3246968 | biostudies-literature

1,1'-Dimethyl-4,4'-bipyridinium bis-(tetra-fluorido-borate).

Project description:In the title compound, C(12)H(14)N(2) (2+)·2BF(4) (-), the cation has a centre of symmetry at the mid-point of the central C-C bond. ?-? inter-actions, with a shortest atom-to-atom distance of 3.757?(4)?Å, extend the crystal structure into a one-dimensional supra-molecular chain.

| S-EPMC2915310 | biostudies-literature

[(1,2,5,6-?)-Cyclo-octa-1,5-diene]bis-(1-isopropyl-3-methyl-imidazolin-2-yl-idene)rhodium(I) tetra-fluorido-borate.

Project description:In the title compound, [Rh(C(8)H(12))(C(7)H(12)N(2))(2)]BF(4), the square-planar Rh complex cation and the BF(4) (-) anion are both bis-ected by a crystallographic twofold rotation axis. The Rh and B atoms lie on this axis and all others are in general positions. In the crystal, two unique C-H?F hydrogen-bonding inter-actions are present, which involve both imidazolin-2-yl-idene H atoms. They form two separate C(5) motifs, the combination of which is a rippled hydrogen-bonded sheet structure in the ab plane.

| S-EPMC3238752 | biostudies-literature

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