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Crystal structure of (?-4-hy-droxy-benzene-thiol-ato-?(2) S:S)bis-(?-phenyl-methane-thiol-ato-?(2) S:S)bis-[(?(6)-1-isopropyl-4-methyl-benzene)-ruthenium(II)] tetra-fluorido-borate.

ABSTRACT: The crystal structure of the dinuclear arene ruthenium title complex, [Ru2(C6H5OS)(C7H7S)2(C10H14)2]BF4, shows the two Ru(II) atoms to be bridged by two benzyl-thio-pheno-late units and one 4-hy-droxy-thio-pheno-late unit, with the remaining three coordination sites of each Ru(II) atom being occupied by p-cymene ligands, completing the typical piano-stool coordination geometry. The BF4 (-) counter-anion is surrounded by four cationic dinuclear complexes, showing an O-H?F hydrogen bond and several weak C-H?F inter-actions. This is the first example of an X-ray analysis of a mixed dinuclear tri-thiol-ate arene ruthenium(II) complex.

SUBMITTER: Stibal D

PROVIDER: S-EPMC4647355 | biostudies-literature | 2015 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of (μ-4-hy-droxy-benzene-thiol-ato-κ(2) S:S)bis-(μ-phenyl-methane-thiol-ato-κ(2) S:S)bis-[(η(6)-1-isopropyl-4-methyl-benzene)-ruthenium(II)] tetra-fluorido-borate.

Stíbal David D Süss-Fink Georg G Therrien Bruno B

Acta crystallographica. Section E, Crystallographic communications 20150912 Pt 10

The crystal structure of the dinuclear arene ruthenium title complex, [Ru2(C6H5OS)(C7H7S)2(C10H14)2]BF4, shows the two Ru(II) atoms to be bridged by two benzyl-thio-pheno-late units and one 4-hy-droxy-thio-pheno-late unit, with the remaining three coordination sites of each Ru(II) atom being occupied by p-cymene ligands, completing the typical piano-stool coordination geometry. The BF4 (-) counter-anion is surrounded by four cationic dinuclear complexes, showing an O-H⋯F hydrogen bond and severa ...[more]

PMID: 26594399

Similar Datasets

Crystal structure of bis-[μ-(4-meth-oxy-phen-yl)methane-thiol-ato-κ(2) S:S]bis-[chlorido-(η(6)-1-isopropyl-4-methyl-benzene)-ruthenium(II)] chloro-form disolvate.

Project description:The mol-ecular structure of the title complex, [Ru2(C8H9OS)2Cl2(C10H14)2]·2CHCl3 or (p-MeC6H4Pr (i) )2Ru2(SCH2-p-C6H5-OCH3)2Cl2·2CHCl3, shows inversion symmetry. The two symmetry-related Ru(II) atoms are bridged by two 4-meth-oxy-α-toluene-thiol-ato [(4-meth-oxy-phen-yl)methane-thiol-ato] units. One chlorido ligand and the p-cymene ligand complete the typical piano-stool coordination environment of the Ru(II) atom. In the crystal, the CH moiety of the chloro-form mol-ecule inter-acts with the chlorido ligand of the dinuclear complex, while one Cl atom of the solvent inter-acts more weakly with the methyl group of the bridging 4-meth-oxy-α-toluene-thiol-ato unit. This assembly leads to the formation of supra-molecular chains extending parallel to [021].

| S-EPMC4647371 | biostudies-literature

(μ-4-Methyl-benzene-thiol-ato-κS:S)bis-[carbon-yl(η-cyclo-penta-dien-yl)molybdenum(II)].

Project description:The asymmetric unit of the title compound, [Mo(2)(C(5)H(5))(2)(C(7)H(7)S)(2)(CO)(2)], consists of two half-mol-ecules, each molecule lying on a centre of symmetry. The thiol-ate groups function as bridges between the Mo(II) atoms, which adopt a quasi-octa-hedral geometry. In the octa-hedral environment the two ligating S atoms are in a cis arrangement.

| S-EPMC2961228 | biostudies-literature

Synthesis and crystal structure of bis-(μ-2-methyl-benzene-thiol-ato-κ2S:S)bis-[meth-yl(2-methyl-benzene-thiol-ato-κS)indium(III)].

Project description:The dinuclear title compound, [In2(CH3)2(C7H7S)4] or [Me(2-MeC6H4S)In-μ-(2-MeC6H4S)2InMe(2-MeC6H4S)], was prepared from the 1:2 reaction of Me3In and 2-MeC6H4SH in toluene. Its crystal structure exhibits a four-membered In2S2 ring core via bridging (2-MeC6H4S) groups. The dimeric units are further associated into a one-dimensional polymeric structure extending parallel to the a axis via inter-molecular In⋯S contacts. The In atoms are then in distorted trigonal-bipyramidal CS4 bonding environments.

| S-EPMC5382603 | biostudies-literature

trans-Bis(μ-benzene-thiol-ato-κ(2) S:S)bis[chlorido-(tri-phenyl-phosphane-κP)palladium(II)] chloro-form disolvate.

Project description:The title compound, [Pd2Cl2(C6H5S)2(C18H15P)2]·2CHCl3, contains a centrosymmetric dinuclear palladium complex with the Pd(II) cation in a slightly distorted square-planar coordination environment. The Pd(II) cations are bridged by the S atoms of two benzene-thiol-ate ligands with different Pd-S distances [2.2970 (11) and 2.3676 (11) Å]. The coordination of the metal atom is completed by a chloride anion [2.3383 (11) Å] and a tri-phenyl-phosphane ligand [2.2787 (11) Å]. Weak C-H⋯Cl inter-actions are present between complex mol-ecules and the CHCl3 solvent mol-ecule. The latter is disordered over two positions in a 0.792 (8):0.208 (8) ratio. The crystal under investigation was found to be twinned by nonmerohedry, with a fraction of 73.4 (1)% for the major twin component.

| S-EPMC3793701 | biostudies-literature

catena-Poly[[bis-(4-methyl-benzene-thiol-ato)cadium(II)]-μ-1,3-di-4-pyridylpropane].

Project description:In the title compound, [Cd(C(7)H(7)S)(2)(C(13)H(14)N(2))](n), the unique Cd(II) ion, located on a twofold rotation axis, is coordinated by two S atoms and two N atoms in a slightly distorted tetra-hedral environment. Symmetry-related Cd(II) ions are linked via bridging 1,3-di-4-pyridylpropane ligands, forming a zig-zag chain-structure parallel to [001]. In the crystal structure, there are weak intra-chain π-π stacking inter-actions between benzene rings, with a centroid-centroid distance of 3.825 (7) Å, and pairs of chains are inter-digitated with respect to the 4-methyl-benzene-thiol-ate groups.

| S-EPMC2968951 | biostudies-literature

Crystal structure of catena-poly[[[di-aqua-cobalt(II)]-bis-(μ-hex-3-enedi-nitrile-κ(2) N:N')] bis-(tetra-fluorido-borate)].

Project description:In the structure of the title salt, [Co(C6H6N2)2(H2O)2](BF4)2, the Co(II) atom is located on an inversion centre. The transition metal is in a slightly distorted octa-hedral coordination environment, defined by the cyano N atoms of four hex-3-enedi-nitrile ligands in equatorial positions and the O atoms of two water mol-ecules in axial positions. The bridging mode of the hex-3-enedi-nitrile ligands leads to the formation of cationic chains extending parallel to [1-10]. The BF4 (-) counter-anion is disordered over two sets of sites [occupancy ratio = 0.512 (19):0.489 (19)]. It is located in the voids between the cationic chains and is connected to the aqua ligands of the latter through O-H⋯F hydrogen bonds. One methyl-ene H atom of the hex-3-enedi-nitrile ligand forms another and weak C-H⋯O hydrogen bond with a water O atom of a neighbouring chain, thus consolidating the three-dimensional network structure.

| S-EPMC4459353 | biostudies-literature

catena-Poly[[copper(II)-bis-[μ-bis-(pyridin-3-yl)methanone-κN:N']] bis-(tetra-fluorido-borate)].

Project description:In the title complex, {[Cu(C(11)H(8)N(2)O)(2)](BF(4))(2)}(n), the Cu(II) ion is situated on an inversion centre and adopts an N(4)F(2) octa-hedral coordination geometry with four N atoms from four different bis-(pyridin-3-yl)methanone ligands at the equatorial sites and two independent tetra-fluoridoborate anions weakly bonded at the axial sites via two F atoms [Cu⋯F = 2.613 (3) Å]. Chains with the bridging ligands are formed along the a axis. C-H⋯F inter-actions stabilize the structure. C-O⋯π inter-actions also occur.

| S-EPMC3238772 | biostudies-literature

μ(4)-Sulfido-bis-{(μ-2-furyl-methane-thiol-ato)bis-[tricarbonyl-iron](Fe-Fe)}.

Project description:The title compound, [Fe(4)(C(5)H(5)OS)(2)S(CO)(12)], was prepared by the direct reaction of Fe(3)(CO)(12) and 2-furyl-methane-thiol in tetra-hydro-furan. Desulfurization took place readily to form an Fe(4)S(3) cluster. The mol-ecule consists of two similar [(μ-2-C(4)H(3)O-CH(2)S)Fe(2)(CO)(6)] moieties joined to a spiro-type four-coordinate μ(4)-S atom such that this bridging sulfur is tetra-hedrally coordinated to the four Fe atoms. In each diiron subcluster core, the 2-furyl-methane-thiol-ate ligand bridges the two Fe atoms.

| S-EPMC3007034 | biostudies-literature

μ-Oxido-bis-[hydridotris(tri-methyl-phosphane-κP)iridium(III)](Ir-Ir) bis-(tetra-fluorido-borate) dihydrate.

Project description:The title compound, [Ir2H2O(C3H9P)6](BF4)2·2H2O, was isolated from the reaction between [Ir(COD)(PMe3)3]BF4 and H2 in water (COD is cyclo-octa-1,5-diene). The asymmetric unit consists of one Ir(III) atom bonded to three PMe3 groups, one hydride ligand and half an oxide ligand, in addition to a BF4 (-) counter-ion and one water molecule of hydration. The single oxide ligand bridging two Ir(III) atoms is disordered across an inversion center with each O atom having a 50% site occupancy. Each Ir(III) atom has three PMe3 groups occupying facial positions, with the half-occupancy O atoms, a hydride ligand and an Ir-Ir bond completing the coordination sphere. The Ir-Ir distance is 2.8614 (12) Å, comparable to other iridium(III) metal-metal bonds. Two water mol-ecules hydrogen bond to two BF4 (-) anions in the unit cell.

| S-EPMC3998581 | biostudies-literature

Poly[bis-(μ(4)-benzene-1,4-dicarboxyl-ato)(μ(4)-succinato)diterbium(III)].

Project description:In the title compound, [Tb(2)(C(4)H(4)O(4))(C(8)H(4)O(4))(2)](n), the coord-in-ation around each Tb atom is distorted square-anti-prismatic. The benzene-1,4-dicarboxyl-ate and succinate anions bridge the anti-prisms, forming a three-dimensional network. The succinate anion is located on a centre of inversion. The structure is isomorphous with the Dy, Gd, Er and Nd complexes.

| S-EPMC2961078 | biostudies-literature

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