Browse
Submit Data
Databases
API
Help

Dataset Information

27 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Hydration of Proton-conducting BaCe_0.9Y_0.1O_3-? by Decoupled Mass Transport.

ABSTRACT: Mass relaxation profile of a perovskite-type oxide, BaCe_0.9Y_0.1O_3-?, was studied to understand decoupled diffusion of oxygen and hydrogen species during hydration/dehydration. The mass relaxation measurements are performed by thermogravimetric analysis (TGA) under various humidity conditions (Dry, -3.0???log(pH₂O/atm)???-1.6) at a constant oxygen partial pressure (log(pO₂/atm)?=?-1.00?±?0.01). The decoupled ions participated in hydration/dehydration reactions were proven to be at different ratios from the result introduced by the 8R _m function. The enthalpy and entropy of non-stoichiometric hydration reaction, which considers each ratio of charge-carrier species, were -144.7?±?3.7?kJ/mol and -147.8?±?3.2?J/mol?·?K, respectively.

SUBMITTER: Lim DK

PROVIDER: S-EPMC5428669 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Hydration of Proton-conducting BaCe0.9Y0.1O3-δ by Decoupled Mass Transport.

Lim Dae-Kwang DK Im Ha-Ni HN Song Sun-Ju SJ Yoo Han-Ill HI

Scientific reports 20170328 1

Mass relaxation profile of a perovskite-type oxide, BaCe0.9Y0.1O3-δ, was studied to understand decoupled diffusion of oxygen and hydrogen species during hydration/dehydration. The mass relaxation measurements are performed by thermogravimetric analysis (TGA) under various humidity conditions (Dry, -3.0 ≤ log(pH2O/atm) ≤ -1.6) at a constant oxygen partial pressure (log(pO2/atm) = -1.00 ± 0.01). The decoupled ions participated in hydration/deh ...[more]

PMID: 28352081

Similar Datasets

Effect of NiO Addition on the Sintering and Electrochemical Properties of BaCe0.55Zr0.35Y0.1O3-δ Proton-Conducting Ceramic Electrolyte.

Project description:Proton ceramic fuel cells offer numerous advantages compared with conventional fuel cells. However, the practical implementation of these cells is hindered by the poor sintering activity of the electrolyte. Despite extensive research efforts to improve the sintering activity of BCZY, the systematic exploration of the utilization of NiO as a sintering additive remains insufficient. In this study, we developed a novel BaCe0.55Zr0.35Y0.1O3-δ (BCZY) electrolyte and systematically investigated the impact of adding different amounts of NiO on the sintering activity and electrochemical performance of BCZY. XRD results demonstrate that pure-phase BCZY can be obtained by sintering the material synthesized via solid-state reaction at 1400 °C for 10 h. SEM analysis revealed that the addition of NiO has positive effects on the densification and grain growth of BCZY, while significantly reducing the sintering temperature required for densification. Nearly fully densified BCZY ceramics can be obtained by adding 0.5 wt.% NiO and annealing at 1350 °C for 5 h. The addition of NiO exhibits positive effects on the densification and grain growth of BCZY, significantly reducing the sintering temperature required for densification. An anode-supported full cell using BCZY with 0.5 wt.% NiO as the electrolyte reveals a maximum power density of 690 mW cm-2 and an ohmic resistance of 0.189 Ω cm2 at 650 °C. Within 100 h of long-term testing, the recorded current density remained relatively stable, demonstrating excellent electrochemical performance.

| S-EPMC10972099 | biostudies-literature

Aliovalent-doped sodium chromium oxide (Na0.9Cr0.9Sn0.1O2 and Na0.8Cr0.9Sb0.1O2) for sodium-ion battery cathodes with high-voltage characteristics.

Project description:NaCrO2 with high rate-capability is an attractive cathode material for sodium-ion batteries (NIBs). However, the amount of reversibly extractable Na+ ions is restricted by half, which results in relatively low energy density for practical NIB cathodes. Herein, we describe aliovalent-doped O3-Na0.9[Cr0.9Sn0.1]O2 (NCSnO) and O3-Na0.8[Cr0.9Sb0.1]O2 (NCSbO), both of which show high-voltage characteristics that translate to an increase in energy density. In contrast to NaCrO2, NCSnO and NCSbO can be reversibly charged to 3.80 and 3.95 V, respectively, delivering 0.5 Na+ along with Cr3+/4+ redox alone. The reversible chargeability to Na0.4[Cr0.9Sn0.1]O2 and Na0.3[Cr0.9Sb0.1]O2 is not associated with the suppression of Cr6+ formation. Both compounds show concentrations of Cr6+ that are higher than that of Na0.3CrO2, with an absence of O3' phases. This implies that aliovalent-doping contributes to a suppression of the Cr6+ migration into tetrahedral sites in the interslab space, which reduces the possibility of irreversible comproportionation. NCSnO and NCSbO deliver capacities comparable to that of NaCrO2, but show a higher average discharge voltage (2.94 V for NaCrO2; 3.14 V for NCSnO; 3.21 V for NCSbO), which leads to a noticeable increase in energy densities. The high-voltage characteristics of NCSnO and NCSbO are also validated via density-functional-theory calculations.

| S-EPMC9058423 | biostudies-literature

Evaluation of High-Temperature Hydrogen Sensors Based on BaCe0.6Zr0.3Y0.1O3-? and Sr(Ce0.9Zr0.1)0.95Yb0.05O3-? Perovskites for Industrial Applications.

Project description:In many industrial fields, there is a need to design and characterize on-line and on-board hydrogen monitoring tools able to operate under extreme conditions. One of these applications is in future nuclear fusion reactors, which will use hydrogen isotopes as a plasma fuel. In this context, the measurement of the concentration of these hydrogen isotopes will be of interest to ensure the correct operating conditions for such reactors. Hydrogen sensors based on solid-state electrolytes will be the first step in the development of new analytical tools able to quantify deuterium and tritium in aggressive environments. In the present work, amperometric hydrogen sensors were constructed and evaluated using two solid-state electrolytes, BaCe0.6Zr0.3Y0.1O3-? and Sr(Ce0.9Zr0.1)0.95Yb0.05O3-?. Prototype sensors were built in order to study their sensitivity in on-line measurements. The experiments were performed in a reactor with a hydrogen-controlled environment. The sensors were evaluated at 500 and 600 °C in amperometric mode by applying 2 and 4 V voltages between electrodes. Both sensors showed increases in sensitivity when the temperature or voltage were increased.

| S-EPMC7766507 | biostudies-literature

Shaping triple-conducting semiconductor BaCo0.4Fe0.4Zr0.1Y0.1O3-δ into an electrolyte for low-temperature solid oxide fuel cells.

Project description:Interest in low-temperature operation of solid oxide fuel cells is growing. Recent advances in perovskite phases have resulted in an efficient H+/O2-/e- triple-conducting electrode BaCo0.4Fe0.4Zr0.1Y0.1O3-δ for low-temperature fuel cells. Here, we further develop BaCo0.4Fe0.4Zr0.1Y0.1O3-δ for electrolyte applications by taking advantage of its high ionic conduction while suppressing its electronic conduction through constructing a BaCo0.4Fe0.4Zr0.1Y0.1O3-δ-ZnO p-n heterostructure. With this approach, it has been demonstrated that BaCo0.4Fe0.4Zr0.1Y0.1O3-δ can be applied in a fuel cell with good electrolyte functionality, achieving attractive ionic conductivity and cell performance. Further investigation confirms the hybrid H+/O2- conducting capability of BaCo0.4Fe0.4Zr0.1Y0.1O3-δ-ZnO. An energy band alignment mechanism based on a p-n heterojunction is proposed to explain the suppression of electronic conductivity and promotion of ionic conductivity in the heterostructure. Our findings demonstrate that BaCo0.4Fe0.4Zr0.1Y0.1O3-δ is not only a good electrode but also a highly promising electrolyte. The approach reveals insight for developing advanced low-temperature solid oxide fuel cell electrolytes.

| S-EPMC6461657 | biostudies-literature

Lu-atom-ordered oxonitridoaluminosilicate Ba0.9Ce0.1LuAl0.2Si3.8N6.9O0.1.

Project description:A single crystal of Ba0.9Ce0.1LuAl0.2Si3.8N6.9O0.1 (barium cerium lutetium aluminosilicate nitride oxide) was obtained by heating a mixed powder of Ba3N2, Si3N4, Al, Lu2O3, and CeO2 at 2173 K for 1 h under N2 gas at 0.85 MPa. X-ray single-crystal structure analysis revealed that the title oxynitride is hexa-gonal (lattice constants: a = 6.0378 (5) Å, c = 9.8133 (9) Å; space group: P63 mc) and isostructural with BaYbSi4N7. (Ba,Ce) and Lu atoms occupy twelvefold and sixfold coordination sites, respectively.

| S-EPMC7643228 | biostudies-literature

Ferromagnetic-like behavior of Bi0.9La0.1FeO3-KBr nanocomposites.

Project description:We studied magnetostatic response of the Bi0.9La0.1FeO3- KBr composites (BLFO-KBr) consisting of nanosized (≈100 nm) ferrite Bi0.9La0.1FeO3 (BLFO) conjugated with fine grinded ionic conducting KBr. When the fraction of KBr is rather small (less than 15 wt%) the magnetic response of the composite is very weak and similar to that observed for the BLFO (pure KBr matrix without Bi1-xLaxFeO3 has no magnetic response as anticipated). However, when the fraction of KBr increases above 15%, the magnetic response of the composite changes substantially and the field dependence of magnetization reveals ferromagnetic-like hysteresis loop with a remanent magnetization about 0.14 emu/g and coercive field about 1.8 Tesla (at room temperature). Nothing similar to the ferromagnetic-like hysteresis loop can be observed in Bi1-zLazFeO3 ceramics with z ≤ 0.15, which magnetization quasi-linearly increases with magnetic field. Different physical mechanisms were considered to explain the unusual experimental results for BLFO-KBr nanocomposites, but only those among them, which are highly sensitive to the interaction of antiferromagnetic Bi0.9La0.1FeO3 with ionic conductor KBr, can be relevant.

| S-EPMC6639540 | biostudies-literature

Zirconium and Yttrium Co-Doped BaCo0.8Zr0.1Y0.1O3-δ: A New Mixed-Conducting Perovskite Oxide-Based Membrane for Efficient and Stable Oxygen Permeation.

Project description:Oxygen permeation membranes (OPMs) are regarded as promising technology for pure oxygen production. Among various materials for OPMs, perovskite oxides with mixed electron and oxygen-ion (e-/O2-) conducting capability have attracted particular interest because of the high O2- conductivity and structural/compositional flexibility. However, BaCoO3-δ-based perovskites as one of the most investigated OPMs suffer from low oxygen permeation rate and inferior structural stability in CO2-containing atmospheres. Herein, zirconium and yttrium co-doped BaCoO3-δ (BaCo1-2xZrxYxO3-δ, x = 0, 0.05, 0.1 and 0.15) are designed and developed for efficient and stable OPMs by stabilizing the crystal structure of BaCoO3-δ. With the increased Zr/Y co-doping content, the crystal structural stability of doped BaCoO3-δ is much improved although the oxygen permeation flux is slightly reduced. After optimizing the co-doping amount, BaCo0.8Zr0.1Y0.1O3-δ displays both a high rate and superior durability for oxygen permeation due to the well-balanced grain size, oxygen-ion mobility, crystal structural stability, oxygen vacancy concentration and surface exchange/bulk diffusion capability. Consequently, the BaCo0.8Zr0.1Y0.1O3-δ membrane delivers a high oxygen permeation rate of 1.3 mL min-1 cm-2 and relatively stable operation at 800 ∘C for 100 h. This work presents a promising co-doping strategy to boost the performance of perovskite-based OPMs, which can promote the industrial application of OPM technology.

| S-EPMC9501606 | biostudies-literature

Atomic Layer Deposition of GdCoO3 and Gd0.9Ca0.1CoO3.

Project description:Thin films of the catalytically interesting ternary and quaternary perovskites GdCoO3 and Gd0.9Ca0.1CoO3 are fabricated by atomic layer deposition using metal ?-diketonates and ozone as precursors. The resulting thin films are amorphous as deposited and become single-oriented crystalline on LaAlO3(100) and YAlO3(100/010) after post-annealing at 650 °C in air. The crystal orientations of the films are tunable by choice and the orientation of the substrate, mitigated through the interface via solid face epitaxy upon annealing. The films exhibit no sign of Co2+. Additionally, high-aspect-ratio Si(100) substrates were used to document the suitability of the developed process for the preparation of coatings on more complex, high-surface-area structures. We believe that coatings of GdCoO3 and Gd1-xCaxCoO3 may find applications within oxidation catalysis.

| S-EPMC6982051 | biostudies-literature

Plasma engraved Bi0.1(Ba0.5Sr0.5)0.9Co0.8Fe0.2O3-δ perovskite for highly active and durable oxygen evolution.

Project description:The development of highly active and cost-effective catalysts based on noble metal free oxygen electro-catalysis is critical to energy storage and conversion devices. Herein, we highlight a plasma-treated Bi0.1(Ba0.5Sr0.5)0.9Co0.8Fe0.2O3-δ perovskite (denoted as P-Bi0.1BSCF) as a promising catalyst for oxygen evolution reaction (OER) in alkaline media. H2/Ar plasma engraving could significantly increase electrochemically active O22-/O- concentration and tune the electronic structure of Co ions efficiently, and consequently tailor the intrinsic electrocatalytic ability for OER. Of note, P-Bi0.1BSCF, with unique crystalline core/amorphous shell structure, exhibits an enhanced intrinsic OER activity and higher stability than the noble metal IrO2 catalyst, which outperforms most of the reported perovskite catalysts. The present work provides new insights into exploring efficient catalysts for OER, and it suggests that, in addition to the extensively applied for surface treatment of various catalysts such as carbons and metal oxides, the plasma engraved perovskite materials also exhibits great potential as precious metal-free catalysts.

| S-EPMC6414661 | biostudies-literature

Creating Ferromagnetic Insulating La0.9Ba0.1MnO3 Thin Films by Tuning Lateral Coherence Length.

Project description:In this work, heteroepitaxial vertically aligned nanocomposite (VAN) La0.9Ba0.1MnO3 (LBMO)-CeO2 films are engineered to produce ferromagnetic insulating (FMI) films. From combined X-ray photoelectron spectroscopy, X-ray diffraction, and electron microscopy, the elimination of the insulator-metal (I-M) transition is shown to result from the creation of very small lateral coherence lengths (with the corresponding lateral size ∼ 3 nm (∼7 u.c.)) in the LBMO matrix, achieved by engineering a high density of CeO2 nanocolumns in the matrix. The small lateral coherence length leads to a shift in the valence band maximum and reduction of the double exchange (DE) coupling. There is no "dead layer" effect at the smallest achieved lateral coherence length of ∼3 nm. The FMI behavior obtained by lateral dimensional tuning is independent of substrate interactions, thus intrinsic to the film itself and hence not related to film thickness. The unique properties of VAN films give the possibility for multilayer spintronic devices that can be made without interface degradation effects between the layers.

| S-EPMC8023513 | biostudies-literature