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Ferromagnetic-like behavior of Bi0.9La0.1FeO3-KBr nanocomposites.

ABSTRACT: We studied magnetostatic response of the Bi0.9La0.1FeO3- KBr composites (BLFO-KBr) consisting of nanosized (?100?nm) ferrite Bi0.9La0.1FeO3 (BLFO) conjugated with fine grinded ionic conducting KBr. When the fraction of KBr is rather small (less than 15?wt%) the magnetic response of the composite is very weak and similar to that observed for the BLFO (pure KBr matrix without Bi1-xLaxFeO3 has no magnetic response as anticipated). However, when the fraction of KBr increases above 15%, the magnetic response of the composite changes substantially and the field dependence of magnetization reveals ferromagnetic-like hysteresis loop with a remanent magnetization about 0.14?emu/g and coercive field about 1.8 Tesla (at room temperature). Nothing similar to the ferromagnetic-like hysteresis loop can be observed in Bi1-zLazFeO3 ceramics with z???0.15, which magnetization quasi-linearly increases with magnetic field. Different physical mechanisms were considered to explain the unusual experimental results for BLFO-KBr nanocomposites, but only those among them, which are highly sensitive to the interaction of antiferromagnetic Bi0.9La0.1FeO3 with ionic conductor KBr, can be relevant.

SUBMITTER: Karpinsky DV 

PROVIDER: S-EPMC6639540 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature

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We studied magnetostatic response of the Bi<sub>0.9</sub>La<sub>0.1</sub>FeO<sub>3</sub>- KBr composites (BLFO-KBr) consisting of nanosized (≈100 nm) ferrite Bi<sub>0.9</sub>La<sub>0.1</sub>FeO<sub>3</sub> (BLFO) conjugated with fine grinded ionic conducting KBr. When the fraction of KBr is rather small (less than 15 wt%) the magnetic response of the composite is very weak and similar to that observed for the BLFO (pure KBr matrix without Bi<sub>1-x</sub>La<sub>x</sub>FeO<sub>3</sub> has no magn  ...[more]

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