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Fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework.

ABSTRACT: A titanium-based zeolitic thiophene-benzimidazolate framework has been designed for the direct synthesis of dimethyl carbonate (DMC) from methanol and carbon dioxide. The developed catalyst activates carbon dioxide and delivers over 16% yield of DMC without the use of any dehydrating agent or requirement for azeotropic distillation.

SUBMITTER: Verma S 

PROVIDER: S-EPMC5429631 | biostudies-literature | 2017 Apr

REPOSITORIES: biostudies-literature

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Fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework.

Verma Sanny S   Baig R B Nasir RBN   Nadagouda Mallikarjuna N MN   Varma Rajender S RS  

Scientific reports 20170405 1

A titanium-based zeolitic thiophene-benzimidazolate framework has been designed for the direct synthesis of dimethyl carbonate (DMC) from methanol and carbon dioxide. The developed catalyst activates carbon dioxide and delivers over 16% yield of DMC without the use of any dehydrating agent or requirement for azeotropic distillation. ...[more]

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