Ontology highlight
ABSTRACT:
SUBMITTER: Park Y
PROVIDER: S-EPMC5451467 | biostudies-literature | 2017 May
REPOSITORIES: biostudies-literature
Scientific reports 20170531 1
Synthesis of morphologically well-defined crystals of metalloporphyrin by direct crystallization based on conventional anti-solvent crystallization method without using any additives has been rarely reported. Herein, we demonstrate an unconventional and additive-free synthetic method named reverse anti-solvent crystallization method to achieve well-defined zinc-porphyrin cube crystals by reversing the order of the addition of solvents. The extended first solvation shell effect mechanism is there ...[more]