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Conversion of Biowaste Asian Hard Clam (Meretrix lusoria) Shells into White-Emitting Phosphors for Use in Neutral White LEDs.


ABSTRACT: The increasing volume and complexity of waste associated with the modern economy poses a serious risk to ecosystems and human health. However, the remanufacturing and recycling of waste into usable products can lead to substantial resource savings. In the present study, clam shell waste was first transformed into pure and well-crystallized single-phase white light-emitting phosphor Ca?Gd(PO?)?:Eu2+,Mn2+ materials. The phosphor Ca?Gd(PO?)?:Eu2+,Mn2+ materials were synthesized by the solid-state reaction method and the carbothermic reduction process, and then characterized and analyzed by means of X-ray diffraction (XRD) and photoluminescence (PL) measurements. The structural and luminescent properties of the phosphors were investigated as well. The PL and quantum efficiency measurements showed that the luminescence properties of clam shell-based phosphors were comparable to that of the chemically derived phosphors. Moreover, white light-emitting diodes were fabricated through the integration of 380 nm chips and single-phase white light-emitting phosphors (Ca0.979Eu0.006Mn0.015)?Gd(PO?)? into a single package of a white light emitting diode (WLED) emitting a neutral white light of 5298 K with color coordinates of (0.337, 0.344).

SUBMITTER: Chang TY 

PROVIDER: S-EPMC5457013 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature

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Conversion of Biowaste Asian Hard Clam (Meretrix lusoria) Shells into White-Emitting Phosphors for Use in Neutral White LEDs.

Chang Tsung-Yuan TY   Wang Chih-Min CM   Lin Tai-Yuan TY   Lin Hsiu-Mei HM  

Materials (Basel, Switzerland) 20161202 12


The increasing volume and complexity of waste associated with the modern economy poses a serious risk to ecosystems and human health. However, the remanufacturing and recycling of waste into usable products can lead to substantial resource savings. In the present study, clam shell waste was first transformed into pure and well-crystallized single-phase white light-emitting phosphor Ca₉Gd(PO₄)₇:Eu<sup>2+</sup>,Mn<sup>2+</sup> materials. The phosphor Ca₉Gd(PO₄)₇:Eu<sup>2+</sup>,Mn<sup>2+</sup> mat  ...[more]

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