Ontology highlight
ABSTRACT:
SUBMITTER: van Putten R
PROVIDER: S-EPMC5485043 | biostudies-literature | 2017 Jun
REPOSITORIES: biostudies-literature
van Putten Robbert R Uslamin Evgeny A EA Garbe Marcel M Liu Chong C Gonzalez-de-Castro Angela A Lutz Martin M Junge Kathrin K Hensen Emiel J M EJM Beller Matthias M Lefort Laurent L Pidko Evgeny A EA
Angewandte Chemie (International ed. in English) 20170421 26
Catalytic hydrogenation of carboxylic acid esters is essential for the green production of pharmaceuticals, fragrances, and fine chemicals. Herein, we report the efficient hydrogenation of esters with manganese catalysts based on simple bidentate aminophosphine ligands. Monoligated Mn PN complexes are particularly active for the conversion of esters into the corresponding alcohols at Mn concentrations as low as 0.2 mol % in the presence of sub-stoichiometric amounts of KO<sup>t</sup> Bu base. ...[more]