{1,1'-Bis[(pyridin-2-yl)meth-yl]-2,2'-bipiperid-yl}(perchlorato)copper(II) perchlorate.

ABSTRACT: The title complex, [Cu^II(ClO₄)(mesoPYBP)](ClO₄) {PYBP = 1,1'-bis-[(pyridin-2-yl)meth-yl]-2,2'-bipiperidyl, C₂₂H₃₀N₄}, was prepared and found to crystallize with two crystallographically independent complex salt moieties. The metal atoms of the cations adopt a pseudo-square-pyramidal coordination geometry, where the tetra-dentate amino-pyridine ligands (PYBP) are wrapped around the Cu atoms in the equatorial plane. The Cu-O bonds involving an O atom of the coordinating perchlorate anion are approximately perpendicular to the plane. The two remaining non-coordinating perchlorate anions are involved in several C-H?O hydrogen bonds with the PYBP ligand and balance the total charge of the complex salt. The two crystallographically independent moieties are related to each other via a pseudo-translation along the a-axis direction. Exact translational symmetry is broken by (i) a difference in the conformation of one of the piperidine rings, featuring a chair conformation in one of the cations, and a sterically disfavored boat conformation in the other; and (ii) by modulation of the non-coordinating perchlorate anions.

SUBMITTER: Yang G 

PROVIDER: S-EPMC5499296 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature